The contribution of the methanol-to-aromatics reaction to benzene methylation over ZSM-5 catalysts

被引：53

作者：

Adebajo, MO ^{[1
]}

Long, MA ^{[1
]}

机构：

[1] Univ New S Wales, Sch Chem Sci, Sydney, NSW 2052, Australia

来源：

CATALYSIS COMMUNICATIONS | 2003年 / 4卷 / 02期

基金：

澳大利亚研究理事会;

关键词：

benzene methylation; methanol; methane; methanol-only conversion; benzene-only conversion; methane conversion; ZSM-5;

D O I：

10.1016/S1566-7367(02)00259-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The methanol to aromatics conversion is shown to contribute significantly to the benzene methylation with methanol at 400degreesC over acidic ZSM-5 catalysts but such contribution over all catalysts is negligible at 250degreesC. Benzene-only conversion shows only negligible contribution at both temperatures over the catalysts studied. However, it appears that the methanol-only conversion can be minimised, to enhance the benzene methylation with methanol (and indirectly the oxidative benzene methylation with methane), by using NaZSM-5 with highly reduced Bronsted acidity. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：71 / 76

页数：6

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