Organic Semiconductors based on Dyes and Color Pigments

被引:410
作者
Gsaenger, Marcel [1 ,2 ]
Bialas, David [1 ,2 ]
Huang, Lizhen [1 ,2 ]
Stolte, Matthias [1 ,2 ]
Wuerthner, Frank [1 ,2 ]
机构
[1] Univ Wurzburg, Inst Organ Chem, D-97074 Wurzburg, Germany
[2] Univ Wurzburg, Ctr Nanosyst Chem, D-97074 Wurzburg, Germany
关键词
FIELD-EFFECT TRANSISTORS; THIN-FILM TRANSISTORS; 25TH ANNIVERSARY ARTICLE; HETEROJUNCTION SOLAR-CELLS; HIGH-ELECTRON-MOBILITY; QUANTITATIVE STRUCTURE DETERMINATION; DIPOLAR MEROCYANINE DYES; BOND-LENGTH ALTERNATION; PHTHALOCYANINES PART I; NEAR-INFRARED DYES;
D O I
10.1002/adma.201505440
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Organic dyes and pigments constitute a large class of industrial products. The utilization of these compounds in the field of organic electronics is reviewed with particular emphasis on organic field-effect transistors. It is shown that for most major classes of industrial dyes and pigments, i.e., phthalocyanines, perylene and naphthalene diimides, diketopyrrolopyrroles, indigos and isoindigos, squaraines, and merocyanines, charge-carrier mobilities exceeding 1 cm(2) V-1 s(-1) have been achieved. The most widely investigated molecules due to their n-channel operation are perylene and naphthalene diimides, for which even values close to 10 cm(2) V-1 s(-1) have been demonstrated. The fact that all of these p-conjugated colorants contain polar substituents leading to strongly quadrupolar or even dipolar molecules suggests that indeed a much larger structural space shows promise for the design of organic semiconductor molecules than was considered in this field traditionally. In particular, because many of these dye and pigment chromophores demonstrate excellent thermal and (photo-)chemical stability in their original applications in dyeing and printing, and are accessible by straightforward synthetic protocols, they bear a particularly high potential for commercial applications in the area of organic electronics.
引用
收藏
页码:3615 / 3645
页数:31
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