Immobilization of Ag(I) into a metal-organic framework with -SO3H sites for highly selective olefin-paraffin separation at room temperature

被引：164

作者：

Chang, Ganggang ^{[1
]}

Huang, Minhui ^{[1
]}

Su, Ye ^{[1
]}

Xing, Huabin ^{[1
]}

Su, Baogen ^{[1
]}

Zhang, Zhiguo ^{[1
]}

Yang, Qiwei ^{[1
]}

Yang, Yiwen ^{[1
]}

Ren, Qilong ^{[1
]}

Bao, Zongbi ^{[1
]}

Chen, Banglin ^{[2
]}

机构：

[1] Zhejiang Univ, Coll Chem & Biol Engn, Key Lab Biomass Chem Engn, Minist Educ, Hangzhou 310027, Zhejiang, Peoples R China

[2] Univ Texas San Antonio, Dept Chem, San Antonio, TX USA

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 14期

基金：

国家高技术研究发展计划(863计划); 中国国家自然科学基金;

关键词：

HYDROCARBON SEPARATIONS; ADSORPTIVE SEPARATION; ETHYLENE; ETHANE; NANOPARTICLES; FABRICATION; PROPYLENE; EFFICIENT; HYDROGEN; PROPANE;

D O I：

10.1039/c4cc09679g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Introduction of Ag(I) ions into a sulfonic acid functionalized MOF ((Cr)-MIL-101-SO3H) significantly enhances its interactions with olefin double bonds, leading to its much higher selectivities for the separation of C2H4-C2H6 and C3H6-C3H8 at room temperature over the original (Cr)-MIL-101-SO3H and other adsorbents at room temperature.

引用

页码：2859 / 2862

页数：4

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