Selective Decoration of Metal Nanoparticles inside or outside of Organic Microstructures via Self-Assembly of Resorcinarene

A facile template method was described for the decoration of organic microtubes with various nanoparticles (NPs), which was achieved in a straightforward "mix" process in the presence of templates and resorcinarene-functionalized nanoparticles (AuNPs, AgNPs, PtNPs, and PdNPs). A combination of UV-visible spectra and Fourier transform-infrared spectroscopy, transmission electron microscopy, field emission scanning electron microscopy, X-ray diffraction measurements, contact angle experiment, and energy dispersive X-ray spectroscopy was used for analysis. Interestingly, it was found that NPs could be encapsulated into the microtubes during the process of resorcinarene self-assembly. As a model system, AuNP-loaded microtubes were investigated and discussed, and loaded nanoparticles with a narrow size distribution were observed. Furthermore, AuNP-decorated microsheets could also be obtained by the assembly of resorcinarene with hydrazide groups. Remarkably, it was also observed that the incorporated NPs could be redispersed by treating the NP-loaded microtubes, which made it possible to realize the uptake and release of given nanoparticles. This procedure was scalable to diverse resorcinarene-based self-assemblies and applicable to various metal nanoparticles that decorate by resorcinarenes.