Increasing the resistivity and IFSS of unsized carbon fibre by covalent surface modification

被引:22
作者
Beggs, Kathleen M. [1 ]
Randall, James D. [1 ]
Servinis, Linden [1 ]
Krajewski, Andrew [2 ]
Denning, Ron [2 ]
Henderson, Luke C. [1 ]
机构
[1] Deakin Univ, Inst Frontier Mat, Pigdons Rd,Waurn Ponds Campus, Geelong, Vic 3216, Australia
[2] CSIRO Mfg, Geelong, Vic 3216, Australia
基金
澳大利亚研究理事会;
关键词
Carbon fibre; Interfacial adhesion; Surface modification; Resistance; ARYL DIAZONIUM SALTS; ELECTRICAL-CONDUCTIVITY; ELECTROCHEMICAL REDUCTION; IN-SITU; SHEAR-STRENGTH; COMPOSITES; GRAPHENE; FUNCTIONALIZATION; REINFORCEMENT; ELECTRODES;
D O I
10.1016/j.reactfunctpolym.2017.06.016
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Carbon fibre presents many attractive qualities such as high strength to weight ratio and suitability in a variety of light weighting applications. One of the major practical limitation for processing carbon fibres are their electrical conductivity and their ability to short circuit electrical equipment through airborne fibres and other carbon fibre detritus. In this work we investigate the ability to reduce the conductivity of carbon fibres using an electrochemical grafting strategy. In this study unsized carbon fibres were electrochemically functionalised with a variety of small molecules, increasing the resist of carbon fibres by up to 200%. In addition, using this strategy we have also increased the interfacial shear properties of these fibres in epoxy resin systems ( + 19%) relative to the control fibres.
引用
收藏
页码:123 / 128
页数:6
相关论文
共 43 条
[1]  
A. S. D, 1999, STAND TEST METH DC R, P257
[2]   Covalent modification of iron surfaces by electrochemical reduction of aryldiazonium salts [J].
Adenier, A ;
Bernard, MC ;
Chehimi, MM ;
Cabet-Deliry, E ;
Desbat, B ;
Fagebaume, O ;
Pinson, J ;
Podvorica, F .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (19) :4541-4549
[3]   Covalent modification of carbon surfaces by aryl radicals generated from the electrochemical reduction of diazonium salts [J].
Allongue, P ;
Delamar, M ;
Desbat, B ;
Fagebaume, O ;
Hitmi, R ;
Pinson, J ;
Saveant, JM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (01) :201-207
[4]   Toward wearable and stretchable fabric-based supercapacitors: novel ZnO and SnO2 nanowires-carbon fibre and carbon paper hybrid structure [J].
Bae, Joonho ;
Park, Young Jun ;
Yang, Ju Chan ;
Kim, Hyoun Woo ;
Kim, Doo Young .
JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2015, 19 (01) :211-219
[5]   Rapid surface functionalization of carbon fibres using microwave irradiation in an ionic liquid [J].
Beggs, Kathleen M. ;
Perus, Magenta D. ;
Servinis, Linden ;
O'Dell, Luke A. ;
Fox, Bronwyn L. ;
Gengenbach, Thomas R. ;
Henderson, Luke C. .
RSC ADVANCES, 2016, 6 (39) :32480-32483
[6]   A systematic study of carbon fibre surface grafting via in situ diazonium generation for improved interfacial shear strength in epoxy matrix composites [J].
Beggs, Kathleen M. ;
Servinis, Linden ;
Gengenbach, Thomas R. ;
Huson, Mickey G. ;
Fox, Bronwyn L. ;
Henderson, Luke C. .
COMPOSITES SCIENCE AND TECHNOLOGY, 2015, 118 :31-38
[7]   Multiscale carbon nanotube-carbon fiber reinforcement for advanced epoxy composites [J].
Bekyarova, E. ;
Thostenson, E. T. ;
Yu, A. ;
Kim, H. ;
Gao, J. ;
Tang, J. ;
Hahn, H. T. ;
Chou, T. -W. ;
Itkis, M. E. ;
Haddon, R. C. .
LANGMUIR, 2007, 23 (07) :3970-3974
[8]   Electrografting: a powerful method for surface modification [J].
Belanger, Daniel ;
Pinson, Jean .
CHEMICAL SOCIETY REVIEWS, 2011, 40 (07) :3995-4048
[9]   Electrical conductivity and interlaminar shear strength enhancement of carbon fiber reinforced polymers through synergetic effect between graphene oxide and polyaniline [J].
Cheng, Xiuyan ;
Yokozeki, Tomohiro ;
Wu, Lixin ;
Wang, Haopeng ;
Zhang, JinMeng ;
Koyanagi, Jun ;
Weng, Zixiang ;
Sun, Qingfu .
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2016, 90 :243-249
[10]   Modification of carbon fiber surfaces by electrochemical reduction of aryl diazonium salts: Application to carbon epoxy composites [J].
Delamar, M ;
Desarmot, G ;
Fagebaume, O ;
Hitmi, R ;
Pinson, J ;
Saveant, JM .
CARBON, 1997, 35 (06) :801-807