(E)-4-[(4-Fluorobenzylidene)amino]-3-[1-(4-isobutylphenyl)ethyl]-1-(morpholinomethyl)-1H-1,2,4-triazole-5(4H)-thione methanol hemisolvate

被引：1

作者：

Goh, Jia Hao ^{[1
]}

Fun, Hoong-Kun ^{[1
]}

Vinayaka, A. C. ^{[2
]}

Kalluraya, B. ^{[2
]}

机构：

[1] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, George Town 11800, Malaysia

[2] Mangalore Univ, Dept Studies Chem, Mangalore 574199, India

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

MANNICH-BASES; ANTIBACTERIAL; DERIVATIVES; ANTIFUNGAL; SCHIFF; ISATIN;

D O I：

10.1107/S1600536810015217

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, C(26)H(32)FN(5)OS center dot 0.5CH(4)O, the methyl group of the methanol solvent molecule is disordered over two sites with equal occupancies and the solvent is further disordered about a crystallographic twofold rotation axis. The organic molecule exists in a trans configuration with respect to the acyclic C=N bond. An intramolecular C-H center dot center dot center dot S hydrogen bond generates an S(6) ring motif. The morpholine ring adopts a chair conformation. The essentially planar 1,2,4-triazole ring [maximum deviation = 0.013 (2) angstrom] forms dihedral angles of 11.21 (10) and 67.53 (11)degrees, respectively, with the fluorophenyl unit and the isobutyl-substituted benzene ring. The crystal structure is stabilized by a weak intermolecular C-H center dot center dot center dot pi interaction.

引用

页码：O1233 / U1390

页数：13