Highly Efficient Perovskite Nanocrystal Light-Emitting Diodes Enabled by a Universal Crosslinking Method

被引:837
作者
Li, Guangru [1 ]
Rivarola, Florencia Wisnivesky Rocca [2 ]
Davis, Nathaniel J. L. K. [1 ]
Bai, Sai [3 ]
Jellicoe, Tom C. [1 ]
de la Pena, Francisco [2 ]
Hou, Shaocong [4 ]
Ducati, Caterina [2 ]
Gao, Feng [3 ]
Friend, Richard H. [1 ]
Greenham, Neil C. [1 ]
Tan, Zhi-Kuang [1 ,5 ,6 ]
机构
[1] Univ Cambridge, Cavendish Lab, JJ Thomson Ave, Cambridge CB3 0HE, England
[2] Univ Cambridge, Dept Mat Sci & Met, Charles Babbage Rd, Cambridge CB3 0FS, England
[3] Linkoping Univ, Biomol & Organ Elect IFM, S-58183 Linkoping, Sweden
[4] Univ Cambridge, Dept Engn, JJ Thomson Ave, Cambridge CB3 0FA, England
[5] Natl Univ Singapore, Dept Chem, 3 Sci Dr 3, Singapore 117543, Singapore
[6] Natl Univ Singapore, Solar Energy Res Inst Singapore, 7 Engn Dr 1, Singapore 117544, Singapore
基金
英国工程与自然科学研究理事会;
关键词
ORGANOMETAL HALIDE PEROVSKITES; SOLAR-CELLS; PERFORMANCE; EMISSION; POLYMER; ENERGY; CSPBX3;
D O I
10.1002/adma.201600064
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The preparation of highly efficient perovskite nanocrystal light-emitting diodes is shown. A new trimethylaluminum vapor-based crosslinking method to render the nanocrystal films insoluble is applied. The resulting near-complete nanocrystal film coverage, coupled with the natural confinement of injected charges within the perovskite crystals, facilitates electron-hole capture and give rise to a remarkable electroluminescence yield of 5.7%.
引用
收藏
页码:3528 / +
页数:8
相关论文
共 27 条
  • [11] Enhanced Performance in Fluorene-Free Organometal Halide Perovskite Light-Emitting Diodes using Tunable, Low Electron Affinity Oxide Electron Injectors
    Hoye, Robert L. Z.
    Chua, Matthew R.
    Musselman, Kevin P.
    Li, Guangru
    Lai, May-Ling
    Tan, Zhi-Kuang
    Greenham, Neil C.
    MacManus-Driscoll, Judith L.
    Friend, Richard H.
    Credgington, Dan
    [J]. ADVANCED MATERIALS, 2015, 27 (08) : 1414 - +
  • [12] Photoelectron spectroscopic study of the electronic band structure of polyfluorene and fluorene-arylamine copolymers at interfaces
    Hwang, Jaehyung
    Kim, Eung-Gun
    Liu, Jie
    Bredas, Jean-Luc
    Duggal, Anil
    Kahn, Antoine
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (03) : 1378 - 1384
  • [13] Electronic energy transfer in CdSe quantum dot solids
    Kagan, CR
    Murray, CB
    Nirmal, M
    Bawendi, MG
    [J]. PHYSICAL REVIEW LETTERS, 1996, 76 (09) : 1517 - 1520
  • [14] Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
    Kojima, Akihiro
    Teshima, Kenjiro
    Shirai, Yasuo
    Miyasaka, Tsutomu
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (17) : 6050 - +
  • [15] Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites
    Lee, Michael M.
    Teuscher, Joel
    Miyasaka, Tsutomu
    Murakami, Takurou N.
    Snaith, Henry J.
    [J]. SCIENCE, 2012, 338 (6107) : 643 - 647
  • [16] SYNTHESIS AND CHARACTERIZATION OF NEARLY MONODISPERSE CDE (E = S, SE, TE) SEMICONDUCTOR NANOCRYSTALLITES
    MURRAY, CB
    NORRIS, DJ
    BAWENDI, MG
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (19) : 8706 - 8715
  • [17] Chemical Management for Colorful, Efficient, and Stable Inorganic-Organic Hybrid Nanostructured Solar Cells
    Noh, Jun Hong
    Im, Sang Hyuk
    Heo, Jin Hyuck
    Mandal, Tarak N.
    Seok, Sang Il
    [J]. NANO LETTERS, 2013, 13 (04) : 1764 - 1769
  • [18] Pena de la F., 2015, HYPERSPY, DOI [10.5281/zenodo.28025, DOI 10.5281/ZENODO.28025]
  • [19] Nanocrystals of Cesium Lead Halide Perovskites (CsPbX3, X = Cl, Br, and I): Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut
    Protesescu, Loredana
    Yakunin, Sergii
    Bodnarchuk, Maryna I.
    Krieg, Franziska
    Caputo, Riccarda
    Hendon, Christopher H.
    Yang, Ruo Xi
    Walsh, Aron
    Kovalenko, Maksym V.
    [J]. NANO LETTERS, 2015, 15 (06) : 3692 - 3696
  • [20] Quantum Dot Light-Emitting Diodes Based on Inorganic Perovskite Cesium Lead Halides (CsPbX3)
    Song, Jizhong
    Li, Jianhai
    Li, Xiaoming
    Xu, Leimeng
    Dong, Yuhui
    Zeng, Haibo
    [J]. ADVANCED MATERIALS, 2015, 27 (44) : 7162 - +