Highly Efficient Perovskite Nanocrystal Light-Emitting Diodes Enabled by a Universal Crosslinking Method

被引:837
作者
Li, Guangru [1 ]
Rivarola, Florencia Wisnivesky Rocca [2 ]
Davis, Nathaniel J. L. K. [1 ]
Bai, Sai [3 ]
Jellicoe, Tom C. [1 ]
de la Pena, Francisco [2 ]
Hou, Shaocong [4 ]
Ducati, Caterina [2 ]
Gao, Feng [3 ]
Friend, Richard H. [1 ]
Greenham, Neil C. [1 ]
Tan, Zhi-Kuang [1 ,5 ,6 ]
机构
[1] Univ Cambridge, Cavendish Lab, JJ Thomson Ave, Cambridge CB3 0HE, England
[2] Univ Cambridge, Dept Mat Sci & Met, Charles Babbage Rd, Cambridge CB3 0FS, England
[3] Linkoping Univ, Biomol & Organ Elect IFM, S-58183 Linkoping, Sweden
[4] Univ Cambridge, Dept Engn, JJ Thomson Ave, Cambridge CB3 0FA, England
[5] Natl Univ Singapore, Dept Chem, 3 Sci Dr 3, Singapore 117543, Singapore
[6] Natl Univ Singapore, Solar Energy Res Inst Singapore, 7 Engn Dr 1, Singapore 117544, Singapore
基金
英国工程与自然科学研究理事会;
关键词
ORGANOMETAL HALIDE PEROVSKITES; SOLAR-CELLS; PERFORMANCE; EMISSION; POLYMER; ENERGY; CSPBX3;
D O I
10.1002/adma.201600064
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The preparation of highly efficient perovskite nanocrystal light-emitting diodes is shown. A new trimethylaluminum vapor-based crosslinking method to render the nanocrystal films insoluble is applied. The resulting near-complete nanocrystal film coverage, coupled with the natural confinement of injected charges within the perovskite crystals, facilitates electron-hole capture and give rise to a remarkable electroluminescence yield of 5.7%.
引用
收藏
页码:3528 / +
页数:8
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