Equilibrium data for the system rice bran oil plus fatty acids plus ethanol plus water at 298.2 K

被引:49
作者
Rodrigues, CEC [1 ]
Antoniassi, R [1 ]
Meirelles, AJA [1 ]
机构
[1] Univ Estadual Campinas, Fac Food Engn, LASEFI, BR-13083970 Campinas, SP, Brazil
关键词
D O I
10.1021/je0255978
中图分类号
O414.1 [热力学];
学科分类号
摘要
This work presents experimental data for the model system refined rice bran oil + commercial oleic acid + ethanol + water at 298.2 K. These data were correlated by the NRTL and UNIQUAC models, with a global deviation of approximately 0.7% for both models. The equilibrium of crude rice bran oil + aqueous ethanol was predicted with success using the adjusted interaction parameters, with deviation between calculated and experimental results not higher than 0.54%. The results showed that the addition of water to the solvent increases the solvent selectivity, reducing the losses of neutral oil and nutraceutical compounds, and expands the region of phase splitting, allowing the refining of highly acidic crude rice bran oils by solvent extraction.
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页码:367 / 373
页数:7
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