A critical review on suitability and catalytic production of butyl levulinate as a blending molecule for green diesel

被引:30
作者
Ahmad, Khwaja Alamgir [1 ]
Siddiqui, Mohammad Haider [1 ]
Pant, Kamal K. [2 ]
Nigam, K. D. P. [2 ]
Shetti, Nagaraj P. [3 ]
Aminabhavi, Tejraj M. [3 ,4 ]
Ahmad, Ejaz [1 ]
机构
[1] Indian Inst Technol, Indian Sch Mines, Dept Chem Engn, Dhanbad 826004, India
[2] Indian Inst Technol Delhi, Dept Chem Engn, Delhi 110016, India
[3] KLE Technol Univ, Sch Adv Sci, Hubballi 580031, India
[4] UPES, Sch Engn, Dehra Dun 248007, Uttarakhand, India
关键词
Alkyl levulinates; Butyl levulinate; Green diesel; Green chemistry; Esterification; Biofuel; ONE-POT SYNTHESIS; N-BUTYL; FURFURYL ALCOHOL; EFFICIENT CONVERSION; ETHYL LEVULINATE; SURFACE-TENSION; HETEROPOLY ACID; SOLID ACID; ALKYL LEVULINATE; LIQUID-PHASE;
D O I
10.1016/j.cej.2022.137550
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Butyl levulinate (BL), derived from bio-renewable resources, is a potential blending molecule for diesel fuel. Thus, essential characteristics such as boiling point, melting point, flash point, cetane number, calorific value, kinematic viscosity, density, and surface tension of different biorenewable molecules have been assessed. It is found that the BL can be the most suitable blending molecule for diesel fuel. Post this, the current state of the art for BL production via bio-chemo-catalytic routes has been reviewed. In particular, mechanistic insight into the role of feedstock structure such as levulinic acid, furfuryl alcohol, monosaccharides including fructose, glucose, xylose, polysaccharides including cellulose, inulin, sucrose and lignocellulosic biomass on BL production have been developed. It is followed by a critical discussion of the catalyst's physicochemical properties such as physical state, structure, functional groups, acidity, surface area, and pore size to elucidate their effect on each reactant conversion and BL yield. Thus, the current review focuses on the suitability of BL as a potential blending molecule and its production methods for application in green diesel.
引用
收藏
页数:20
相关论文
共 179 条
[1]   Relationships between viscosity and density measurements of biodiesel fuels [J].
Acaroglu, M. ;
Demirbas, A. .
ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS, 2007, 29 (08) :705-712
[2]   Evaluation of Dimethyl Carbonate as Alternative Biofuel. Performance and Smoke Emissions of a Diesel Engine Fueled with Diesel/Dimethyl Carbonate/Straight Vegetable Oil Triple Blends [J].
Aguado-Deblas, Laura ;
Hidalgo-Carrillo, Jesus ;
Bautista, Felipa M. ;
Luna, Carlos ;
Calero, Juan ;
Posadillo, Alejandro ;
Romero, Antonio A. ;
Luna, Diego ;
Estevez, Rafael .
SUSTAINABILITY, 2021, 13 (04) :1-14
[3]   Understanding reaction kinetics, deprotonation and solvation of bronsted acidic protons in heteropolyacid catalyzed synthesis of biorenewable alkyl levulinates [J].
Ahmad, Ejaz ;
Khan, Tuhin Suvra ;
Alam, Md. Imteyaz ;
Pant, K. K. ;
Haider, M. Ali .
CHEMICAL ENGINEERING JOURNAL, 2020, 400
[4]   Insights into the Synthesis of Ethyl Levulinate under Microwave and Nonmicrowave Heating Conditions [J].
Ahmad, Ejaz ;
Alam, Md Imteyaz ;
Pant, K. K. ;
Haider, M. Ali .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2019, 58 (35) :16055-16064
[5]   Catalytic and mechanistic insights into the production of ethyl levulinate from biorenewable feedstocks [J].
Ahmad, Ejaz ;
Alam, Md. Imteyaz ;
Pant, K. K. ;
Haider, M. Ali .
GREEN CHEMISTRY, 2016, 18 (18) :4804-4823
[6]  
Ahmad KA., 2022, Catal. Royal Soc. Chem, V34, P206, DOI [10.1039/9781839165962-00206, DOI 10.1039/9781839165962-00206]
[7]  
Alam M.I., 2017, Microbial Applications Vol, V2, P153, DOI [10.1007/978-3-319-52669-0_8, DOI 10.1007/978-3-319-52669-0_8]
[8]   Titanium hydrogenphosphate: An efficient dual acidic catalyst for 5-hydroxymethylfurfural (HMF) production [J].
Alam, Md. Imteyaz ;
De, Sudipta ;
Singh, Bhagat ;
Saha, Basudeb ;
Abu-Omar, Mandi M. .
APPLIED CATALYSIS A-GENERAL, 2014, 486 :42-48
[9]  
Alam MI., 2015, SUSTAINABLE CATALYTI
[10]   Clean Catalytic Oxidation for Derivatization of Key Biobased Platform Chemicals: Ethanol, Glycerol, and Hydroxymethyl Furfural [J].
Alejandra Ayude, Maria ;
Dournic, Lucila, I ;
Cassanello, Miryan C. ;
Nigam, Krishna D. P. .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2019, 58 (35) :16077-16095