Structural, Morphological, Opto-Electrical and Photoluminescence Studies of Nanoplate Structured Zn-Doped Sn2S3 Thin Films

被引:6
作者
Gnanamuthu, S. Joshua [1 ]
Jeyakumar, S. Johnson [1 ]
Punithavathi, I. Kartharinal [1 ]
Parasuram, K. [2 ]
Nagarethinam, V. S. [3 ]
Balu, A. R. [3 ]
机构
[1] TBML Coll, PG & Res Dept Phys, Poraiyar, Tamil Nadu, India
[2] Govt Arts Coll, PG & Res Dept Phys, Poompukar, Tamil Nadu, India
[3] AVVM Sri Pushpam Coll, PG & Res Dept Phys, Poondi, Tamil Nadu, India
关键词
Doping; Crystal structure; Surface morphology; Photoluminescence; Optical band gap; ELECTRICAL-PROPERTIES; SUBSTRATE-TEMPERATURE; SPRAY-PYROLYSIS; SULFIDE; DEPOSITION; GROWTH;
D O I
10.1007/s12666-016-0946-0
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
Undoped and Zn-doped Sn2S3 thin films were fabricated by spray pyrolysis technique on glass substrates kept at 400 A degrees C. All the films exhibited orthorhombic crystal structure with a preferential orientation along the (2 1 1) plane. Nanoplate structures were observed from the SEM images and the presence of Zn in the doped films was confirmed from the EDX spectra. The average optical transmittance of all the films in the visible region was found to be nearly equal to 80 %. Film resistivity initially decreased from 3.27 x 10(-1) to 0.78 x 10(-1) Omega-cm for the Sn2S3 thin film doped with 1 wt% Zn concentration and for higher doping concentration it increased. The obtained results showed that the Sn2S3 thin film doped with 1 wt% Zn concentration had better physical properties which made them suitable for photovoltaic applications.
引用
收藏
页码:1503 / 1509
页数:7
相关论文
共 28 条
  • [1] SINGLE-CRYSTAL GROWTH OF LAYERED TIN MONOSELENIDE SEMICONDUCTOR USING A DIRECT VAPOR TRANSPORT TECHNIQUE
    AGARWAL, A
    PATEL, PD
    LAKSHMINARAYANA, D
    [J]. JOURNAL OF CRYSTAL GROWTH, 1994, 142 (3-4) : 344 - 348
  • [2] Influence of argon ambience on the structural, morphological and optical properties of pulsed laser ablated zinc sulfide thin films
    Chalana, S. R.
    Vinodkumar, R.
    Navas, I.
    Ganesan, V.
    Pillai, V. P. Mahadevan
    [J]. JOURNAL OF LUMINESCENCE, 2012, 132 (04) : 944 - 952
  • [3] Electrochemical preparation and characterization of three-dimensional nanostructured Sn2S3 semiconductor films with nanorod network
    Chen, Bin
    Xu, Xinhua
    Wang, Feng
    Liu, Jingjun
    Ji, Jing
    [J]. MATERIALS LETTERS, 2011, 65 (02) : 400 - 402
  • [4] Luminescence studies of localized gap states in colloidal ZnS nanocrystals
    Denzler, D
    Olschewski, M
    Sattler, K
    [J]. JOURNAL OF APPLIED PHYSICS, 1998, 84 (05) : 2841 - 2845
  • [5] Properties of spray deposited nano needle structured Cu-doped Sn2S3 thin films towards photovoltaic applications
    Gnanamuthu, S. Joshua
    Jeyakumar, S. Johnson
    Punithavathy, I. Kartharinal
    Prabhakar, P. C. Jobe
    Suganya, M.
    Usharani, K.
    Balu, A. R.
    [J]. OPTIK, 2016, 127 (08): : 3999 - 4003
  • [6] Structural and optical studies of chemically deposited Sn2S3 thin films
    Guneri, Emine
    Gode, Fatma
    Boyarbay, Behiye
    Gumus, Cebrail
    [J]. MATERIALS RESEARCH BULLETIN, 2012, 47 (11) : 3738 - 3742
  • [7] Conduction-type control of SnSx films prepared by the sol-gel method for different sulfur contents
    Huang, Chung-Cheng
    Lin, Yow-Jon
    Chuang, Cheng-Yu
    Liu, Chia-Jyi
    Yang, Yao-Wei
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2013, 553 : 208 - 211
  • [8] Synthesis of tetrapod like PbS microcrystals by hydrothermal route and its optical characterization
    Jana, S.
    Goswami, S.
    Nandy, S.
    Chattopadhyay, K. K.
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 481 (1-2) : 806 - 810
  • [9] Influence of substrate temperature on the structural, optical and electrical properties of CdS thin films deposited by thermal evaporation
    Jassim, Salah Abdul-Jabbar
    Zumaila, Abubaker A. Rashid Ali
    Al Waly, Gassan Abdella Ali
    [J]. RESULTS IN PHYSICS, 2013, 3 : 173 - 178
  • [10] JoshuaGnanamuthu S., 2016, MATER RES INNOV, V20, P398