octakiS[2-carbazol-9-yl]ethyidimethylsiloxy]silsesquioxane (POSS-Cz) was newly synthesized and its photoluminescence properties in both solution and solid states were investigated. POSS-Cz showed monomeric emission peak not only in solution state but also in solid state. This result suggests that the introduction of octasilsesquioxane core will suppress the aggregation of carbazole even in solid state.