Fundamentals, advances and challenges of transition metal compounds-based supercapacitors

被引:381
作者
Liu, Rong [1 ]
Zhou, Ao [1 ]
Zhang, Xiaorong [1 ]
Mu, Jingbo [1 ]
Che, Hongwei [1 ]
Wang, Yanming [1 ]
Wang, Ting-Ting [2 ]
Zhang, Zhixiao [1 ]
Kou, Zongkui [3 ]
机构
[1] Hebei Univ Engn, Coll Mat Sci & Engn, Technol Innovat Ctr Modified Plast Hebei Prov, Inst Novel Mat Energy & Environm, Handan 056038, Peoples R China
[2] Shenzhen Univ, Coll Phys & Optoelect Engn, Int Collaborat Lab Mat Optoelect Sci & Technol 2D, Shenzhen Engn Lab Phosphorene & Optoelect, Shenzhen 518060, Peoples R China
[3] Natl Univ Singapore, Dept Mat Sci & Engn, Singapore 117574, Singapore
关键词
Supercapacitor; Transition metal compounds; Electrode materials; Transition metal oxides and hydroxides; Derivatives; LAYERED DOUBLE HYDROXIDES; ELECTROCHEMICAL ENERGY-STORAGE; BATTERY-TYPE ELECTRODES; IN-SITU; NI FOAM; GRAPHENE OXIDE; BETA-CO(OH)(2) NANOSHEETS; PHASE-TRANSFORMATION; CO3O4; NANOPARTICLES; ASSISTED SYNTHESIS;
D O I
10.1016/j.cej.2021.128611
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Supercapacitors (SCs), as an attractive energy storage device, have drawn great interests on basis of large power density, fast charging/discharging capability and good cycling performance. Transition metal compounds (TMCs) have promised as electrode materials of supercapacitors to raise the insufficient energy density by the reverse reaction among their multiple oxidation states. To further the rational design of TMCs-based electrode materials, this review looks into advances and challenges in their applications of SCs. The witnessed active TMCs including transition metal oxides, transition metal hydroxides, and their derivatives, are selectively and individually discussed in detail. To deeply illuminate the mechanistic understanding into charge storage, fundamentals of supercapacitors have been categorized into three typical types including electric double layer, pseudocapacitive and asymmetrical storage, where battery-type and pseudocapacitive electrodes are also distinguished by giving two crucial criterions. As a dynamically advancing research frontier for energy storage, we therefore provide a relatively long perspective to identify great opportunities and obstacles in the practical scale up of SCs.
引用
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页数:22
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