Synthesis and switching properties of new derivatives of azoresveratrol

被引：7

作者：

Berthet, Jerome ^{[1
]}

Agouridas, Laurence ^{[2
]}

Chen, Siyao ^{[2
]}

Allouchi, Hassan ^{[3
]}

Melnyk, Patricia ^{[2
]}

Champagne, Benoit ^{[4
]}

Delbaere, Stephanie ^{[1
]}

机构：

[1] Univ Lille, LASIR Lab Spectrochim Infra Rouge & Roman, CNRS, UMR 8516, F-59000 Lille, France

[2] Univ Lille, Ctr Rech Jean Pierre Aubert Neurosci & Canc, CHU Lille, INSERM,JPArc,UMR S 1172, F-59000 Lille, France

[3] Univ Tours, Fac Pharm, EA SIMBA Lab Chim Phys 7502, 31 Ave Monge, F-37200 Tours, France

[4] Univ Namur, Theoret & Struct Phys Chem Unit, Lab Theoret Chem, Namur Inst Struct Matter, Rue Bruxelles 61, B-5000 Namur, Belgium

来源：

DYES AND PIGMENTS | 2019年 / 171卷

关键词：

Azobenzene; Photoswitching; Thermal relaxation; UV irradiation; NMR; DFT calculations; TO-TRANS ISOMERIZATION; THERMAL CIS; AZOBENZENE DERIVATIVES; MECHANISM; SOLVENT; RESVERATROL; SUBSTITUENT; STABILITY; PROOF;

D O I：

10.1016/j.dyepig.2019.107666

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The synthesis and response upon light irradiation of azoresveratrol and six derivatives are reported. While UV irradiation of para-hydroxy trans compounds leads to thermally unstable cis isomers, the para-methoxy and the para-phosphoric ester substituents result in reaching a high conversion and increasing the thermal stability. In addition, the phosphoric ester azo derivative presents similar properties in organic and aqueous solutions, opening the way towards biological applications.

引用

页数：9

共 56 条

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