Crystal structures, spectroscopic, TG and DSC studies of lanthanide picrate complexes with 4-methylmorpholine N-oxide (MMNO)

被引：17

作者：

Fernandes, LC

Matos, JR

Zinner, LB

Vicentini, G

Zukerman-Schpector, J

机构：

[1] Univ Sao Paulo, Inst Quim, BR-05599970 Sao Paulo, Brazil

[2] Univ Fed Rio Grande Norte, Dept Quim, BR-59072970 Natal, RN, Brazil

[3] Univ Fed Sao Carlos, Dept Quim, Lab Cristalog Estereodinam & Modelagem Mol, BR-13565905 Sao Carlos, SP, Brazil

来源：

POLYHEDRON | 2000年 / 19卷 / 22-23期

基金：

巴西圣保罗研究基金会;

关键词：

crystal structures; lanthanide complexes; picrate; 4-methylmorpholine; N-oxide; TG; DSC;

D O I：

10.1016/S0277-5387(00)00494-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structures, IR absorption spectra, emission spectrum of the europium compound, TG and DSC analyses of Ln(pic)(3). MMNO2H2O (pic = picrate, Ln = La, Nd, Eu) complexes are reported. The crystals that were grown from methanolic solutions, are isomorphous belonging to the triclinic space group P (1) over bar. The Ln ions are coordinated to nine oxygen atoms, six of the picrate moieties, one of the MMNO and two of water molecules, giving rise to a tricapped trigonal prism. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：2313 / 2318

页数：6

共 41 条

[11] DASILVA EM, 1993, AN ASS BRAS QUIM, V41, P17
[12] DASILVA EM, 1996, AN ASS BRAS QUIM, V45, P138
[13] daSilva MAA, 1995, J COORD CHEM, V36, P311
[14] DASILVA MAA, 1997, AN ASS BRAS QUIM, V46, P1
[15] FERNANDES LC, 1999, UNPUB
[16] COMPLEXES OF LANTHANIDE (III) IONS WITH NITROGEN DONOR LIGANDS
FORSBERG, JH
[J]. COORDINATION CHEMISTRY REVIEWS, 1973, 10 (1-2) : 195 - 226
[17] STRUCTURAL SYSTEMATICS OF RARE-EARTH COMPLEXES .1. STRUCTURAL CHARACTERIZATION OF LANTHANOID(III) PICRATE HYDRATES - MONOCLINIC (P2(1)/C) (QUASI-)DODECAHYDRATES OF THE RELATED LA -] PR AND ND -] TB FAMILIES
HARROWFIELD, JM
LU, WM
SKELTON, BW
WHITE, AH
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1994, 47 (02) : 321 - 337
[18] STRUCTURAL SYSTEMATICS OF RARE-EARTH COMPLEXES .4. STRUCTURAL CHARACTERIZATION OF LANTHANOID(III) PICRATE HYDRATES - THE QUASI-UNDECAHYDRATE OF SAMARIUM(III) PICRATE
HARROWFIELD, JM
SKELTON, BW
WHITE, AH
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1994, 47 (02) : 359 - 364
[19] Synthesis and characterization of lanthanide picrate complexes with tripiperidinophosphine oxide
Jardino, SA
Isolani, PC
Vicentini, G
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1997, 249 (1-2) : 91 - 93
[20] LIMA FJS, 1994, AN ASS BRAS QUIM, V43, P22

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