Syntheses of Copillar[5]arenes by Co-oligomerization of Different Monomers

被引：266

作者：

Zhang, Zibin ^{[1
]}

Xia, Binyuan ^{[1
]}

Han, Chengyou ^{[1
]}

Yu, Yihua ^{[2
]}

Huang, Feihe ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China

[2] E China Normal Univ, Dept Phys, Shanghai Key Lab Magnet Resonance, Shanghai 200062, Peoples R China

来源：

ORGANIC LETTERS | 2010年 / 12卷 / 15期

基金：

中国国家自然科学基金;

关键词：

COMPLEXATION; GUEST; CALIXARENES; CHEMISTRY;

D O I：

10.1021/ol100883k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Three copillar[5]arenes, pillar[5]arenes containing different repeating units, were successfully prepared by co-oligomerization of different monomers. It was demonstrated that the yields of pillararenes could be improved by using hydroquinone diethers with appropriate aliphatic chain lengths. Pseudorotaxane-type threaded structures were obtained in the solid state by the inclusion of an n-hexane molecule into the cavity of either a homopillar[5]arene, a pillar[5]arene containing only one repeating unit, or a copillar[5]arene.

引用

页码：3285 / 3287

页数：3

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