Facile and chemoselective microwave-assisted cleavage of oximes to their corresponding carbonyl compounds using N,N′-dibromo- N,N′-1,3propylene-bis[(4-methylphenyl)sulfonamide] as a deoximating reagent

被引：7

作者：

Khazaei, A ^{[1
]}

Manesh, AA ^{[1
]}

Ghasemi, AH ^{[1
]}

机构：

[1] Bu Ali Sina Univ, Fac Sci, Dept Chem, Hamadan, Iran

来源：

SYNTHESIS-STUTTGART | 2004年 / 17期

关键词：

aldoximes; carbonyl compounds; ketoximes; microwave irradiation; selective;

D O I：

10.1055/s-2004-834880

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aldoximes and ketoximes are converted to the parent carbonyl compounds in good yields when treated with N,N-dibromo-N,N'-1,3-propylene-bis[(4-methylphenyl)sulfonamide] (2) under microwave irradiation. The simple workup minimizes the loss of product and oximes have been selectively oxidized in the presence of alcohols and alkenes.

引用

页码：2784 / 2786

页数：3

共 11 条

[1] Facile regeneration of carbonyl compounds from oximes and tosylhydrazones with TBHP [J].