Porous nitrogen-doped carbon microspheres as anode materials for lithium ion batteries

被引:86
作者
Chen, Taiqiang [1 ]
Pan, Likun [1 ]
Loh, T. A. J. [2 ]
Chua, D. H. C. [2 ]
Yao, Yefeng [1 ]
Chen, Qun [1 ]
Li, Dongsheng [1 ]
Qin, Wei [1 ]
Sun, Zhuo [1 ]
机构
[1] E China Normal Univ, Dept Phys, Engn Res Ctr Nanophoton & Adv Instrument, Minist Educ,Shanghai Key Lab Magnet Resonance, Shanghai 200062, Peoples R China
[2] Natl Univ Singapore, Dept Mat Sci & Engn, Singapore 117574, Singapore
基金
中国国家自然科学基金;
关键词
RATE CAPABILITY; GRAPHENE SHEETS; STORAGE PERFORMANCE; SUPERHIGH CAPACITY; SODIUM STORAGE; NANOTUBES; NANOFIBERS; STABILITY; NANOSHEETS; COMPOSITE;
D O I
10.1039/c4dt01223b
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Nitrogen-doped carbon microspheres (NCSs) were fabricated via a simple, fast and energy-saving microwave-assisted method followed by thermal treatment under an ammonia atmosphere. NCSs thermally treated at different temperatures were investigated as anode materials for lithium ion batteries (LIBs). The results show that NCSs treated at 900 degrees C exhibit a maximum reversible capacity of 816 mA h g(-1) at a current density of 50 mA g(-1) and preserve a capacity of 660 mA h g(-1) after 50 cycles, and even at a high current density of 1000 mA g(-1), a capacity of 255 mA h g(-1) is maintained. The excellent electrochemical performance of NCSs is due to their porous structure and nitrogen-doping. The present NCSs should be promising low-cost anode materials with a high capacity and good cycle stability for LIBs.
引用
收藏
页码:14931 / 14935
页数:5
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