Nanofibers of conjugated polymers prepared by electrospinning with a two-capillary spinneret

被引:308
作者
Li, D
Babel, A
Jenekhe, SA
Xia, YN [1 ]
机构
[1] Univ Washington, Dept Chem, Seattle, WA 98195 USA
[2] Univ Washington, Dept Chem Engn, Seattle, WA 98195 USA
[3] Univ Washington, Dept Chem, Seattle, WA 98195 USA
关键词
D O I
10.1002/adma.200400606
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Uniform nanoribers composed of poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] and its blends with poly(3-hexylthiophene) are formed by co-electrospinning their solutions with poly(vinyl pyrrolidone) (PVP) through a coaxial capillary system, followed by extraction of the PVP phase (see Figure). Compared with spin-cast films, the fibers show reduced phase separation and improved energy-transfer efficiency.
引用
收藏
页码:2062 / +
页数:6
相关论文
共 70 条
[1]   Ambipolar charge transport in air-stable polymer blend thin-film transistors [J].
Babel, A ;
Wind, JD ;
Jenekhe, SA .
ADVANCED FUNCTIONAL MATERIALS, 2004, 14 (09) :891-898
[2]   LIGHT-EMITTING-DIODES WITH VARIABLE COLORS FROM POLYMER BLENDS [J].
BERGGREN, M ;
INGANAS, O ;
GUSTAFSSON, G ;
RASMUSSON, J ;
ANDERSSON, MR ;
HJERTBERG, T ;
WENNERSTROM, O .
NATURE, 1994, 372 (6505) :444-446
[3]  
Bognitzki M, 2001, ADV MATER, V13, P70, DOI 10.1002/1521-4095(200101)13:1<70::AID-ADMA70>3.0.CO
[4]  
2-H
[5]   VISIBLE-LIGHT EMISSION FROM SEMICONDUCTING POLYMER DIODES [J].
BRAUN, D ;
HEEGER, AJ .
APPLIED PHYSICS LETTERS, 1991, 58 (18) :1982-1984
[6]   Bipolar conducting polymers: Blends of p-type polypyrrole and an n-type ladder polymer [J].
Chen, XL ;
Jenekhe, SA .
MACROMOLECULES, 1997, 30 (06) :1728-1733
[7]   An electrospun poly(vinylidene fluoride) nanofibrous membrane and its battery applications [J].
Choi, SW ;
Jo, SM ;
Lee, WS ;
Kim, YR .
ADVANCED MATERIALS, 2003, 15 (23) :2027-2032
[8]   Palladium nanoparticles by electrospinning from poly(acrylonitrile-co-acrylic acid)-PdCl2 solutions.: Relations between preparation conditions, particle size, and catalytic activity [J].
Demir, MM ;
Gulgun, MA ;
Menceloglu, YZ ;
Erman, B ;
Abramchuk, SS ;
Makhaeva, EE ;
Khokhlov, AR ;
Matveeva, VG ;
Sulman, MG .
MACROMOLECULES, 2004, 37 (05) :1787-1792
[9]  
Desai K, 2004, MATER RES SOC SYMP P, V788, P209
[10]   Generation of electrospun fibers of nylon 6 and nylon 6-montmorillonite nanocomposite [J].
Fong, H ;
Liu, WD ;
Wang, CS ;
Vaia, RA .
POLYMER, 2002, 43 (03) :775-780