Noncovalent Functionalization of Graphene and Graphene Oxide for Energy Materials, Biosensing, Catalytic, and Biomedical Applications

被引：2033

作者：

Georgakilas, Vasilios ^{[1
]}

Tiwari, Jitendra N. ^{[2
]}

Kemp, K. Christian ^{[2
,4
]}

Perman, Jason A. ^{[3
]}

Bourlinos, Athanasios B. ^{[3
]}

Kim, Kwang S. ^{[2
]}

Zboril, Radek ^{[3
]}

机构：

[1] Univ Patras, Dept Mat Sci, Rion 26504, Greece

[2] Ulsan Natl Inst Sci & Technol, Dept Chem, Ctr Superfunct Mat, Ulsan 689798, South Korea

[3] Palacky Univ, Reg Ctr Adv Technol & Mat, Fac Sci, Dept Phys Chem, 17 Listopadu 1192-12, Olomouc 77146, Czech Republic

[4] Pohang Univ Sci & Technol POSTECH, Dept Environm Engn, Pohang 37673, South Korea

来源：

CHEMICAL REVIEWS | 2016年 / 116卷 / 09期

基金：

新加坡国家研究基金会;

关键词：

NITROGEN-DOPED GRAPHENE; OXYGEN REDUCTION REACTION; LIQUID-PHASE EXFOLIATION; NON-OXIDIZED GRAPHENE; FEW-LAYER GRAPHENE; NANOPARTICLE-DECORATED GRAPHENE; HYDROGEN-EVOLUTION REACTION; PERFORMANCE ANODE MATERIAL; LITHIUM-ION BATTERIES; MOS2 ATOMIC LAYERS;

D O I：

10.1021/acs.chemrev.5b00620

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This Review focuses on noncovalent functionalization of graphene and graphene oxide with various species involving biomolecules, polymers, drugs, metals and metal oxide-based nanoparticles, quantum dots, magnetic nanostructures, other carbon allotropes (fullerenes, nanodiamonds, and carbon nanotubes), and graphene analogues (MoS2, WS2). A brief description of pi-pi interactions, van der Waals forces, ionic interactions, and hydrogen bonding allowing noncovalent modification of graphene and graphene oxide is first given. The main part of this Review is devoted, to tailored functionalization for applications in drug delivery, energy materials, solar cells, water splitting, biosensing, bioimaging, environmental, catalytic, photocatalytic, and biomedical technologies. A significant part of this Review explores the possibilities of graphene/graphene oxide-based 3D superstructures and their use in lithium-ion batteries. This Review ends with a look at challenges and future prospects of noncovalently modified graphene and graphene oxide.

引用

页码：5464 / 5519

页数：56

共 447 条

[111] Co/CoO Nanoparticles Assembled on Graphene for Electrochemical Reduction of Oxygen [J].