How to improve efficiency of thermal analysis in decomposition kinetics

被引：17
作者：
L'vov, BV [1 ]
机构：
[1] St Petersburg State Univ, Dept Analyt Chem, St Petersburg 195251, Russia
来源：
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2005年 / 79卷 / 01期
关键词：
accuracy; Arrhenius-plots method; decomposition reactions; E parameter; kinetics; precision; productivity; third-law method;
D O I：
10.1007/s10973-004-0577-2
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The prerequisites to use of the third-law method in decomposition kinetics and great advantages of this method compared to the routine Arrhenius-plots and second-law methods in precision, accuracy and productivity of TA measurements are discussed. Some important achievements obtained with the use of this methodology over the last two years that support potentialities of this approach are briefly reviewed.
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页码：151 / 156
页数：6
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