Mono- and Dinuclear Binding Modes of the 2,5-Bis(α-pyridyl)pyrrolate Ligand in Platinum(II) Complexes

被引：2

作者：

Newman, Drew C. ^{[1
]}

Gau, Michael R. ^{[1
]}

Carroll, Patrick J. ^{[1
]}

Goldberg, Karen, I ^{[1
]}

机构：

[1] Univ Penn, Dept Chem, Philadelphia, PA 19104 USA

来源：

ORGANOMETALLICS | 2021年 / 40卷 / 12期

基金：

美国国家科学基金会;

关键词：

PD(II); ANIONS; PT(II);

D O I：

10.1021/acs.organomet.1c00152

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of platinum(II) complexes with the 2,5-bis(alpha-pyridyl)pyrrolate (PDP) ligand were synthesized. The ligand (X) trans to the central pyrrole nitrogen of PDP was found to play a key role in whether tridentate monomeric or bidentate clamshell dimer complexes were formed. When X = CH3 or C6H5, strong sigma-donor ligands, only dimeric clamshell structures were observed. In contrast, when X = CI or I, ligands with pi-donor properties, both dimeric and monomeric complexes could be prepared. The ability of the ligand framework to support monomeric complexes with pi-donor X-type ligands is attributed to the PDP ligand's ability to act as a competent pi-acid in the monomeric conformation.

引用

收藏

页码：1806 / 1810

页数：5

相关论文

共 19 条

[1] The relative coordinating ability of some weak O-donor anions and water towards the [Pt(terpy)]2+ (terpy=2,2':6',2"-terpyridine) center -: X-ray crystal structures of [Pt(terpy)(H2O)](CF3SO3)2 and [Pt2(μ-OH)(terpy)2](PF6)2(CF3SO3) [J].

Annibale, Giuliano ;

Bergamini, Paola ;

Bertolasi, Valerio ;

Bortoluzzi, Marco ;

Cattabriga, Michela ;

Pitteri, Bruno .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2007, 36 (36) :5743-5751

[2] SYNTHESIS, CHARACTERIZATION, AND INTERACTION WITH DNA OF THE NOVEL METALLOINTERCALATOR CATIONIC COMPLEX (2,2'6',2''-TERPYRIDINE)METHYLPLATINUM(II) [J].

ARENA, G ;

SCOLARO, LM ;

PASTERNACK, RF ;

ROMEO, R .

INORGANIC CHEMISTRY, 1995, 34 (11) :2994-3002

[3] Synthesis, characterization, absorption spectra, and luminescence properties of organometallic platinum(II) terpyridine complexes [J].

Arena, G ;

Calogero, G ;

Campagna, S ;

Scolaro, LM ;

Ricevuto, V ;

Romeo, R .

INORGANIC CHEMISTRY, 1998, 37 (11) :2763-2769

[4]

Fagnou K, 2002, ANGEW CHEM INT EDIT, V41, P26, DOI 10.1002/1521-3773(20020104)41:1<26::AID-ANIE26>3.0.CO

[5]

2-9

[6] The trans influence of F, Cl, Br and I ligands in a series of square-planar Pd(II) complexes.: Relative affinities of halide anions for the metal centre in trans-[(Ph3P)2Pd(Ph)X] [J].

Flemming, JP ;

Pilon, MC ;

Borbulevitch, OY ;

Antipin, MY ;

Grushin, VV .

INORGANICA CHIMICA ACTA, 1998, 280 (1-2) :87-98

[7]

Hartwig J.F., 2009, Organotransition Metal Chemistry: From Bonding to Catalysis, V1st

[8] Recent developments in the supramolecular chemistry of terpyridine-metal complexes [J].

Hofmeier, H ;

Schubert, US .

CHEMICAL SOCIETY REVIEWS, 2004, 33 (06) :373-399

[9] Complexes of 2,5-Bis(α-pyridyl)pyrrolate with Pd(II) and Pt(II): A Monoanionic Iso-π-Electron Ligand Analog of Terpyridine [J].

Imler, Gregory H. ;

Lu, Zhi ;

Kistler, Kurt A. ;

Carroll, Patrick J. ;

Wayland, Bradford B. ;

Zdilla, Michael J. .

INORGANIC CHEMISTRY, 2012, 51 (19) :10122-10128

[10] Cyclometalated Ni(II) Complexes [Ni(N∧C∧N)X] of the Tridentate 2,6-di(2-pyridyl)phen-ide Ligand [J].

Kletsch, Lukas ;

Hoerner, Gerald ;

Klein, Axel .

ORGANOMETALLICS, 2020, 39 (15) :2820-2829