Hydrogen doping in HfO2 resistance change random access memory

被引:27
作者
Duncan, D. [1 ]
Magyari-Koepe, B. [1 ]
Nishi, Y. [1 ]
机构
[1] Stanford Univ, Dept Elect Engn, Stanford, CA 94305 USA
基金
美国国家科学基金会;
关键词
OXYGEN VACANCY; OXIDE; DEFECTS;
D O I
10.1063/1.4940369
中图分类号
O59 [应用物理学];
学科分类号
摘要
The structures and energies of hydrogen-doped monoclinic hafnium dioxide were calculated using density-functional theory. The electronic interactions are described within the LDA + U formalism, where on-site Coulomb corrections are applied to the 5d orbital electrons of Hf atoms and 2p orbital electrons of the O atoms. The effects of charge state, defect-defect interactions, and hydrogenation are investigated and compared with experiment. It is found that hydrogenation of HfO2 resistance-change random access memory devices energetically stabilizes the formation of oxygen vacancies and conductive vacancy filaments through multiple mechanisms, leading to improved switching characteristic and device yield. (C) 2016 AIP Publishing LLC.
引用
收藏
页数:5
相关论文
共 48 条
[1]   Influence of hydrogen annealing on the properties of hafnium oxide thin films [J].
Al-Kuhaili, M. F. ;
Durrani, S. M. A. ;
Bakhtiari, I. A. ;
Dastageer, M. A. ;
Mekki, M. B. .
MATERIALS CHEMISTRY AND PHYSICS, 2011, 126 (03) :515-523
[2]  
[Anonymous], IEEE S VLSI TECHN
[3]   Realization of the Switching Mechanism in Resistance Random Access Memory™ Devices: Structural and Electronic Properties Affecting Electron Conductivity in a Hafnium Oxide-Electrode System Through First-Principles Calculations [J].
Aspera, Susan Menez ;
Kasai, Hideaki ;
Kishi, Hirofumi ;
Awaya, Nobuyoshi ;
Ohnishi, Shigeo ;
Tamai, Yukio .
JOURNAL OF ELECTRONIC MATERIALS, 2013, 42 (01) :143-150
[4]   First-principles calculations of defects in oxygen-deficient silica exposed to hydrogen [J].
Blöchl, PE .
PHYSICAL REVIEW B, 2000, 62 (10) :6158-6179
[5]  
Cagli C., 2011, TECH DIG INT ELECTRO, V2011
[6]   First principles study of the structural, electronic, and dielectric properties of amorphous HfO2 [J].
Chen, Tsung-Ju ;
Kuo, Chin-Lung .
JOURNAL OF APPLIED PHYSICS, 2011, 110 (06)
[7]   Hydrogen-Induced Resistive Switching in TiN/ALD HfO2/PEALD TiN RRAM Device [J].
Chen, Yang Yin ;
Goux, L. ;
Swerts, J. ;
Toeller, M. ;
Adelmann, C. ;
Kittl, J. ;
Jurczak, M. ;
Groeseneken, G. ;
Wouters, D. J. .
IEEE ELECTRON DEVICE LETTERS, 2012, 33 (04) :483-485
[8]   On the identification of the oxygen vacancy in HfO2 [J].
Clark, S. J. ;
Lin, L. ;
Robertson, J. .
MICROELECTRONIC ENGINEERING, 2011, 88 (07) :1464-1466
[9]   Magnetism in hafnium dioxide [J].
Coey, JMD ;
Venkatesan, M ;
Stamenov, P ;
Fitzgerald, CB ;
Dorneles, LS .
PHYSICAL REVIEW B, 2005, 72 (02)
[10]   Ferromagnetism driven by intrinsic point defects in HfO2 -: art. no. 217205 [J].
Das Pemmaraju, C ;
Sanvito, S .
PHYSICAL REVIEW LETTERS, 2005, 94 (21)