Self-assembled monolayers of a multifunctional organic radical

被引：54
作者：
Crivillers, Nuria
Mas-Torrent, Marta
Perruchas, Sandrine
Roques, Nans
Vidal-Gancedo, Jose
Veciana, Jaume
Rovira, Concepcio
Basabe-Desmonts, Lourdes
Ravoo, Bart Jan
Crego-Calama, Mercedes
Reinhoudt, David N.
机构：
[1] CSIC, Inst Ciencia Mat Barcelona, Bellaterra 08193, Spain
[2] Univ Twente, Inst Nanotechnol, Lab Supramol Chem & Technol MESA, NL-7500 AE Enschede, Netherlands
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 13期
关键词：
molecular devices; monolayers; radicals; self-assembly; surface chemistry;
D O I：
10.1002/anie.200603599
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A radical switch: Covalent and noncovalent interactions have been used to functionalize silicon oxide surfaces with polychlorotriphenylmethyl radicals, which are electroactive and can be reversibly reduced or oxidized to nonmagnetic and nonfluorescent species. Thus, the self-assembled monolayers behave as chemical switches that combine electronic absorption, fluorescence emission (see picture), and magnetic outputs. (Chemical Equation Presented). © 2007 Wiley-VCH Verlag GmbH &. Co. KGaA.
引用
收藏
页码：2215 / 2219
页数：5
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