Effect of overcharge on Li(Ni0.5Mn0.3Co0.2)O2/Graphite cells-effect of binder

被引：8

作者：

Rago, Nancy Dietz ^{[1
]}

Graczyk, Donald G. ^{[2
]}

Tsai, Yifen ^{[2
]}

Naik, Seema R. ^{[2
]}

Li, Jianlin ^{[3
]}

Du, Zhijia ^{[3
]}

Wood, David L., III ^{[3
]}

Steele, Leigh Anna ^{[4
]}

Lamb, Joshua ^{[4
]}

Spangler, Scott ^{[4
]}

Grosso, Christopher ^{[4
]}

Fenton, Kyle ^{[4
]}

Bloom, Ira ^{[1
]}

机构：

[1] Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA

[2] Argonne Natl Lab, Chem & Fuel Cycle Technol Div, Analyt Chem Lab, Lemont, IL 60439 USA

[3] Oak Ridge Natl Lab, Energy & Transportat Sci Div, Oak Ridge, TN 37831 USA

[4] Sandia Natl Labs, Power Sources Technol Grp, Albuquerque, NM 87185 USA

来源：

JOURNAL OF POWER SOURCES | 2020年 / 448卷 / 448期

关键词：

Lithium-ion battery; Overcharge; Microstructure; SEI; Anode; Binder; LITHIUM ION CELLS; MASS-SPECTROMETRY; CHEMICAL-CHANGES; ELECTROLYTE; PERFORMANCE; CATHODES;

D O I：

10.1016/j.jpowsour.2019.227414

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Cells based on NMC/graphite, containing styrene-butadiene rubber/carboxymethylcellulose binder in the anodes and pVdF latex/carboxymethykellulose in the cathodes, were systematically overcharged to 100, 120, 140, 160, 180, 250% and 270% state-of-charge. The impact of the binder was characterized by elemental analysis, SEM, and HPLC. These results were compared to similar cells just using the poly (vinylidene difluoride) binder. Not only did the binder impact the rate of transition metal transport from the cathode to the anode, it also had a marked effect on the microstructure and composition of the materials on the anode surface.

引用

页数：9

共 24 条

[1] The state of understanding of the lithium-ion-battery graphite solid electrolyte interphase (SEI) and its relationship to formation cycling
An, Seong Jin
Li, Jianlin
Daniel, Claus
Mohanty, Debasish
Nagpure, Shrikant
Wood, David L., III
[J]. CARBON, 2016, 105 : 52 - 76
[2] Review of selected electrode-solution interactions which determine the performance of Li and Li ion batteries
Aurbach, D
[J]. JOURNAL OF POWER SOURCES, 2000, 89 (02) : 206 - 218
[3] A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions
Aurbach, D
Zinigrad, E
Cohen, Y
Teller, H
[J]. SOLID STATE IONICS, 2002, 148 (3-4) : 405 - 416
[4] Effect of overcharge on Li(Ni0.5Mn0.3Co0.2)O2/graphite lithium ion cells with poly(vinylidene fluoride) binder. III - Chemical changes in the cathode
Bareno, Javier
Rago, Nancy Dietz
Dogan, Fulya
Graczyk, Donald G.
Tsai, Yifen
Naik, Seema R.
Han, Sang-Don
Lee, Eungje
Du, Zhijia
Sheng, Yangping
Li, Jianlin
Wood, David L., III
Steele, Leigh Anna
Lamb, Joshua
Spangler, Scott
Grosso, Christopher
Fenton, Kyle
Bloom, Ira
[J]. JOURNAL OF POWER SOURCES, 2018, 385 : 165 - 171
[5] Effect of overcharge on Li(Ni0.5Mn0.3Co0.2)O2 cathodes: NMP-soluble binder. II - Chemical changes in the anode
Bloom, Ira
Bareno, Javier
Rago, Nancy Dietz
Dogan, Fulya
Graczyk, Donald G.
Tsai, Yifen
Naik, Seema R.
Han, Sang-Don
Lee, Eungje
Du, Zhijia
Sheng, Yangping
Li, Jianlin
Wood, David L., III
Steele, Leigh Anna
Lamb, Joshua
Spangler, Scott
Grosso, Christopher
Fenton, Kyle
[J]. JOURNAL OF POWER SOURCES, 2018, 385 : 156 - 164
[6] Broniarz MO., 2016, Eur J Chem, V7, P182, DOI [DOI 10.5155/eurjchem.7.2.182-186.1396, 10.5155/eurjchem.7.2.182-186.1396, DOI 10.5155/EURJCHEM.7.2.182-186.1396]
[7] Corrosion of aluminum electrodes in aqueous slurries for lithium-ion batteries
Church, Benjamin C.
Kaminski, Daniel T.
Jiang, Junwei
[J]. JOURNAL OF MATERIALS SCIENCE, 2014, 49 (08) : 3234 - 3241
[8] Enabling aqueous binders for lithium battery cathodes - Carbon coating of aluminum current collector
Doberdo, Italo
Loeffler, Nicholas
Laszczynski, Nina
Cericola, Dario
Penazzi, Nerino
Bodoardo, Silvia
Kim, Guk-Tae
Passerini, Stefano
[J]. JOURNAL OF POWER SOURCES, 2014, 248 : 1000 - 1006
[9] Enabling aqueous processing for crack-free thick electrodes
Du, Zhijia
Rollag, K. M.
Li, J.
An, S. J.
Wood, M.
Sheng, Y.
Mukherjee, P. P.
Daniel, C.
Wood, D. L., III
[J]. JOURNAL OF POWER SOURCES, 2017, 354 : 200 - 206
[10] Qualitative and quantitative investigation of organophosphates in an electrochemically and thermally treated lithium hexafluorophosphate-based lithium ion battery electrolyte by a developed liquid chromatography-tandem quadrupole mass spectrometry method
Kraft, Vadim
Weber, Waldemar
Streipert, Benjamin
Wagner, Ralf
Schultz, Carola
Winter, Martin
Nowak, Sascha
[J]. RSC ADVANCES, 2016, 6 (01): : 8 - 17

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