Bis(2,2′-bipyridine)nitratocopper(II) nitrate

被引：9

作者：

Marjani, K

Davies, SC

Durrant, MC

Hughes, DL

Khodamorada, N

Samodi, A

机构：

[1] John Innes Ctr Plant Sci Res, Dept Biol Chem, Norwich NR4 7UH, Norfolk, England

[2] Teacher Training Univ, Fac Chem, Tehran 15614, Iran

[3] John Innes Ctr Plant Sci Res, Computat Biol Grp, Norwich NR4 7UH, Norfolk, England

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷

关键词：

D O I：

10.1107/S1600536804030788

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title complex, [Cu(C10H8N2)(2)(NO3)]NO3, is the first reported unsolvated [Cu(bipy)(2)(NO3)]NO3 structure (bipy is 2,2'-bipyridine). The Cu-II atom of the [Cu(bipy)(2)(NO3)](+) complex is six-coordinated, forming a distorted octahedral geometry; bond lengths to the N atoms of the pyridine rings and one of the O atoms of the chelating NO3 ligand lie in the range 1.975 (5)-2.139 (6) Angstrom, with the second O atom from the NO3 ligand less tightly coordinated at a distance of 2.520 (6) Angstrom. The geometry of the CuN2N'2OO' chromophore more closely resembles that of [Cu(bipy)(2)(NO2)](+) complexes than previously reported [Cu(bipy)(2)(NO3)](+) structures.

引用

页码：M11 / M14

页数：4

共 19 条

[1] COPPER(II) NITRATE COMPOUNDS WITH HETEROCYCLIC LIGANDS - STRUCTURES OF [CU(NO3)(2,2'-DIPYRIDYL)(2)][NO3]CENTER-DOT-H2O AND [CU(H2O)(1,10-PHENANTHROLINE)(2)][NO3](2) [J].