(+)-(1R,2S,3S,4S)-2-Chloro-3-(phenylselanyl)cyclohexane-1,4-diol

被引：0

作者：

Robinson, Tony V.

Taylor, Dennis K.

Tiekink, Edward R. T.

机构：

[1] Univ Texas, Dept Chem, San Antonio, TX 78249 USA

[2] Univ Adelaide, Dept Chem, Adelaide, SA 5005, Australia

[3] Univ Adelaide, Dept Wine & Hort, Glen Osmond, SA 5064, Australia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷

关键词：

D O I：

10.1107/S1600536807030851

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The cyclohexyl ring in the title compound, C12H15ClO2Se, has a chair conformation with the 4-hydroxy group occupying an axial position; the other non-H substituents occupy equatorial positions. Molecules aggregate via O-H center dot center dot center dot O hydrogen bonds into a supramolecular helical chain.

引用

收藏

页码：O3350 / U4746

页数：11

相关论文

共 14 条

[1] SIR92 - a program for automatic solution of crystal structures by direct methods [J].

ALTOMARE, A ;

CASCARANO, G ;

GIACOVAZZO, G ;

GUAGLIARDI, A ;

BURLA, MC ;

POLIDORI, G ;

CAMALLI, M .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 :435-435

[2]

Brandenburg K., 2006, DIAMOND

[3]

BRUKER, 2000, SMART SAINK SADABS

[4] CYCLO-FUNCTIONALISATION OF ORTHO-ALKENYL PHENOLS - NEW METHOD FOR INTRODUCING BENZENESELENO-GROUP [J].

CLIVE, DLJ ;

CHITTATTU, G ;

CURTIS, NJ ;

KIEL, WA ;

WONG, CK .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1977, (20) :725-727

[5] ACETOXYSELENENYLATION OF OLEFINS FOR THE PREPARATION OF VINYLIC AND ALLYLIC ACETATES [J].

ENGMAN, L .

JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (04) :884-890

[6] Base- and Co(II)-catalyzed ring-opening reactions of perhydrooxireno[2,3-d][1,2]dioxines:: An efficient route to 4-hydroxy-2,3-epoxy-ketones [J].

Greatrex, BW ;

Jenkins, NF ;

Taylor, DK ;

Tiekink, ERT .

JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (13) :5205-5210

[7] REGIOSPECIFIC ADDITION OF BENZENESELENENYL HALIDE TO 1,1-DISUBSTITUTED OLEFINS [J].

HO, PT ;

KOLT, RJ .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1982, 60 (05) :663-666

[8]

JOHNSON CK, 1976, ORNL5138 ORTEP2

[9] N-PHENYLSELENOPHTHALIMIDE (N-PSP) AND N-PHENYLSELENOSUCCINIMIDE (N-PSS) - 2 VERSATILE CARRIERS OF THE PHENYLSELENO GROUP- OXYSELENATION OF OLEFINS AND A SELENIUM-BASED MACROLIDE SYNTHESIS [J].

NICOLAOU, KC ;

CLAREMON, DA ;

BARNETTE, WE ;

SEITZ, SP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (13) :3704-3706

[10] Osmium catalyzed dihydroxylation of 1,2-dioxines: A new entry for stereoselective sugar synthesis [J].

Robinson, Tony V. ;

Taylor, Dennis K. ;

Tiekink, Edward R. T. .

JOURNAL OF ORGANIC CHEMISTRY, 2006, 71 (19) :7236-7244