Magnetic properties on an organic ferrimagnetic compound and related materials

被引：5
作者：
Hosokoshi, Y
Katoh, K
Inoue, K
机构：
[1] Inst Mol Sci, Okazaki, Aichi 4448585, Japan
[2] Grad Univ Adv Studies, Sch Math & Phys Sci, Okazaki, Aichi 4448585, Japan
来源：
SYNTHETIC METALS | 2003年 / 133卷
关键词：
ferrimagnetism; organic radical; aminoxyl; triradical; ladder; single-component;
D O I：
10.1016/S0379-6779(02)00425-3
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Search for an organic ferrimagnet has been one of the challenging targets in the field of material science. Recently, we have reported the successful results for the crystals of a novel organic triradical of 2-[3',5'-bis(N-tert-butylaminoxyl)phenyl]-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1-oxyl-3-oxide (PNNBNO). This is the first example of a genuine organic ferrimagnetic material having well-defined chemical and crystal structure with T-C = 0.28 K. The properties of PNNBNO are described and the magnetic interactions of this system are discussed in comparison with the related oligoaminoxyl radicals. (C) 2002 Elsevier Science B.V. All rights reserved.
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页码：527 / 530
页数：4
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