One-dimensional salen-type heterospin trimetallic (3d-4f-3d′) chain-like coordination polymers: Syntheses, crystal structures and magnetic properties

被引：30

作者：

Sun, Wen-Bin ^{[1
]}

Yan, Peng-Fei ^{[1
]}

Li, Guang-Ming ^{[1
]}

Zhang, Ju-Wen ^{[1
]}

Gao, Ting ^{[1
]}

Suda, Masayuki ^{[2
]}

Einaga, Yasuaki ^{[2
]}

机构：

[1] Heilongjiang Univ, Sch Chem & Mat Sci, Key Lab Funct Inorgan Mat Chem HLJU, Minist Educ, Harbin 150080, Peoples R China

[2] Keio Univ, Yokohama, Kanagawa 2238522, Japan

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Salen-type ligand; Heterospin; Trimetallic polymer; Structure; Magnetic properties; COMPLEXES SYNTHESIS; GD; CU; CHEMISTRY; SYSTEMS; SERIES;

D O I：

10.1016/j.inoche.2009.11.006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three one-dimensional (1D) heterospin trimetallic chain-like polymers [{LCu(H2O)}Ln(MeOH)(H2O)(2){(mu-CN)(2)Fe(CN)(4)}]center dot 2H(2)O (1, Ln = La; 2, Ln = Nd; 3, Ln = Gd) were prepared by substitution of the nitrato ligands in [LCuLn] complexes with [Fe(CN)(6)](3-) ions (H2L = N,N'-bis(3-methoxysalicylidene)propane-1,2-diamine). Single-crystal X-ray diffraction analysis revealed that the methyl on the salen-type ligand impeded the connection between cyanide groups and Cu(II) ions efficiently. Consequently, three novel one-dimensional (ID) trimetallic chain-like polymers were obtained with the linker [Fe(CN)(6)](3-) ions interacting only with the lanthanide ions. The magnetic investigation for 3 indicated a ferrimagnetic chain may form. (C) 2009 Elsevier B.V, All rights reserved.

引用

收藏

页码：171 / 174

页数：4

相关论文

共 25 条

[1] 3d-4f Combined Chemistry: Synthetic Strategies and Magnetic Properties [J].

Andruh, Marius ;

Costes, Jean-Pierre ;

Diaz, Carmen ;

Gao, Song .

INORGANIC CHEMISTRY, 2009, 48 (08) :3342-3359

[2] A genuine example of a discrete bimetallic (Cu, Gd) complex: Structural determination and magnetic properties [J].

Costes, JP ;

Dahan, F ;

Dupuis, A ;

Laurent, JP .

INORGANIC CHEMISTRY, 1996, 35 (08) :2400-&

[3] Synthesis and characterization of heterodinuclear Ln3+-Fe3+ and Ln3+-Co3+ complexes, bridged by cyanide ligand (Ln3+ = lanthanide ions).: Nature of the magnetic interaction in the Ln3+-Fe3+ complexes [J].

Figuerola, A ;

Diaz, C ;

Ribas, J ;

Tangoulis, V ;

Granell, J ;

Lloret, F ;

Mahía, J ;

Maestro, M .

INORGANIC CHEMISTRY, 2003, 42 (02) :641-649

[4] One dimensional 3d-4f heterometallic compounds:: Synthesis, structure and magnetic properties [J].

Figuerola, Albert ;

Ribas, Joan ;

Solans, Xavier ;

Font-Bardia, Merce ;

Maestro, Miguel ;

Diaz, Carmen .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, (09) :1846-1852

[5] Ion size dominated 1D and 2D Salen lanthanide coordination complexes and their luminescence [J].

Gao, Ting ;

Yan, Peng-Fei ;

Li, Guang-Ming ;

Hou, Guang-Feng ;

Gao, Jin-Sheng .

POLYHEDRON, 2007, 26 (18) :5382-5388

[6] A rational synthetic route leading to 3d-3d′-4f heterospin systems:: self-assembly processes involving heterobinuclear 3d-4f complexes and hexacyanometallates [J].

Gheorghe, R ;

Andruh, M ;

Costes, JP ;

Donnadieu, B .

CHEMICAL COMMUNICATIONS, 2003, (22) :2778-2779

[7] Oligonuclear 3d-4f complexes as tectons in designing supramolecular solid-state architectures: Impact of the nature of linkers on the structural diversity [J].

Gheorghe, R ;

Cucos, P ;

Andruh, M ;

Costes, JP ;

Donnadieu, B ;

Shova, S .

CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (01) :187-203

[8] Dinuclear copper(II) complexes with different bridging connectors [J].

Huang, W ;

Hu, D ;

Gou, S ;

Qian, H ;

Fun, HK ;

Raj, SSS ;

Meng, Q .

JOURNAL OF MOLECULAR STRUCTURE, 2003, 649 (03) :269-278

[9]

Kara H, 2000, Z NATURFORSCH B, V55, P1131

[10] Synthesis, characterization, and structural analyses of two cyanide-bridged bimetallic complexes [J].

Kautz, JA ;

Mullica, DF ;

Cunningham, BP ;

Combs, RA ;

Farmer, JM .

JOURNAL OF MOLECULAR STRUCTURE, 2000, 523 :175-182