A New Metal-Organic Framework: Product of Solvothermal Synthesis in 3D-Printed Autoclaves

被引：9

作者：

Denisov, G. L. ^{[1
]}

Primakov, P. V. ^{[1
,2
]}

Nelyubina, Yu. V. ^{[1
]}

机构：

[1] Russian Acad Sci, Nesmeyanov Inst Organoelement Cpds, Moscow, Russia

[2] Moscow MV Lomonosov State Univ, Moscow, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2021年 / 47卷 / 04期

基金：

俄罗斯基础研究基金会;

关键词：

3D printing; autoclave; metal-organic framework; X-ray diffraction; solvothermal synthesis; zinc terephthalate; REACTIONWARE; MOF-5;

D O I：

10.1134/S1070328421040011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new metal-organic framework {Zn-4(BDC)(3)(OAc)(2)(DMF)(4)} (BDC = terephthalate anion) was synthesized under solvothermal conditions in a 3D-printed polypropylene autoclave. The product was isolated in a pure state and characterized by elemental analysis and X-ray diffraction (CIF file CCDC no. 2025811). The formation of this product, instead of the expected {Zn4O(BDC)(3)} (MOF-5), was probably due to a change in the conditions of solvothermal synthesis caused by disruption of the integrity of the polypropylene autoclave. This is a drawback of this method of screening of metal-organic frameworks, which, however, in some cases givs rise to new representatives of this class of crystalline materials.

引用

页码：253 / 260

页数：8

共 28 条

[1] Distortion Pathways of Transition Metal Coordination Polyhedra Induced by Chelating Topology [J].

Alvarez, Santiago .

CHEMICAL REVIEWS, 2015, 115 (24) :13447-13483

[2] Open Labware: 3-D Printing Your Own Lab Equipment [J].

Baden, Tom ;

Chagas, Andre Maia ;

Gage, Greg ;

Marzullo, Timothy ;

Prieto-Godino, Lucia L. ;

Euler, Thomas .

PLOS BIOLOGY, 2015, 13 (03)

[3] 3-D printing: The new industrial revolution [J].

Berman, Barry .

BUSINESS HORIZONS, 2012, 55 (02) :155-162

[4] High-throughput screening of synthesis parameters in the formation of the metal-organic frameworks MOF-5 and HKUST-1 [J].

Biemmi, Enrica ;

Christian, Sandra ;

Stock, Norbert ;

Bein, Thomas .

MICROPOROUS AND MESOPOROUS MATERIALS, 2009, 117 (1-2) :111-117

[5] The quest for optimal water quantity in the synthesis of metal-organic framework MOF-5 [J].

Bisercic, Marjetka Savic ;

Marjanovic, Budimir ;

Vasiljevic, Bojana Nedic ;

Mentus, Slavko ;

Zasonska, Beata A. ;

Ciric-Marjanovic, Gordana .

MICROPOROUS AND MESOPOROUS MATERIALS, 2019, 278 :23-29

[6]

Bourhis LJ, 2015, ACTA CRYSTALLOGR A, V71, P59, DOI [10.1107/S2053273314022207, 10.1107/S205327331402220759]

[7] Solvothermal in situ metal/ligand reactions: A new bridge between coordination chemistry and organic synthetic chemistry [J].

Chen, Xiao-Ming ;

Tong, Ming-Liang .

ACCOUNTS OF CHEMICAL RESEARCH, 2007, 40 (02) :162-170

[8] Solvothermal Synthesis of the Metal-Organic Framework MOF-5 in Autoclaves Prepared by 3D Printing [J].

Denisov, G. L. ;

Primakov, P. V. ;

Korlyukov, A. A. ;

Novikov, V. V. ;

Nelyubina, Yu. V. .

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2019, 45 (12) :836-842

[9] Nanostructured metal-organic frameworks and their bio-related applications [J].

Gimenez-Marques, M. ;

Hidalgo, T. ;

Serre, C. ;

Horcajada, P. .

COORDINATION CHEMISTRY REVIEWS, 2016, 307 :342-360

[10] Analysis of 3D printing possibilities for the development of practical applications in synthetic organic chemistry [J].

Gordeev, E. G. ;

Degtyareva, E. S. ;

Ananikov, V. P. .

RUSSIAN CHEMICAL BULLETIN, 2016, 65 (06) :1637-1643

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