μSR study of [Mn12O12(O2CC6H5)16(H2O)4]•2C6H5CO2H

被引：5
作者：
Takeda, K [1 ]
Awaga, K
Ohira, S
Watanabe, I
机构：
[1] Hokkaido Univ, Grad Sch Sci, Div Chem, Sapporo, Hokkaido 0600810, Japan
[2] Nagoya Univ, Grad Sch Sci, Dept Chem, Nagoya, Aichi 4648602, Japan
[3] RIKEN, Inst Phys & Chem Res, Wako, Saitama 3510198, Japan
来源：
SYNTHETIC METALS | 2003年 / 133卷
关键词：
Muon spin relaxation; Mn-12; cluster; blocking temperature;
D O I：
10.1016/S0379-6779(02)00362-4
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The crystals of a Mn-12 cluster, [Mn12O12(O2CC6H5)(16)(H2O)(4)]-2C(6)H(5)CO(2)H, are mosaic involving two kinds of molecules with different relaxation rates. The ratios of the two components in the crystals are strongly batch-dependent. We prepared a batch of crystals in which mainly contained the fast relaxation (FR) species and studied the muon spin relaxation (muSR) measurements in the range 0.3-80 K at zero-field (ZF). As the temperature was lowered, the decay of the muon asymmetry showed systematic temperature dependence: the dynamic and the static behavior of the internal-field appear alternately. This is probably due to the magnetization blocking of the FR molecule. (C) 2002 Elsevier Science B.V All rights reserved.
引用
收藏
页码：609 / 610
页数：2
相关论文
共 50 条
  • [21] Synthesis, characterization, Hirshfeld surface and theoretical properties of (C7H10N)4[H2P2Mo5O23] • H2O
    Harchani, Ali
    Kucerakova, Monika
    Dusek, Michal
    Haddad, Amor
    JOURNAL OF CHEMICAL SCIENCES, 2017, 129 (10) : 1539 - 1547
  • [22] Synthesis and Structure Investigation of a Transition Metal Ion Bridging Bis(diphosphopentamolybdates), [H2BIIM]3[HBIIM]4[Mn(H2O)4(P2Mo5O23)2]•7H2O
    Wei Lin-Heng
    Wang Zi-Liang
    Zhao Jun-Wei
    Wang Jing-Ping
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2010, 29 (05) : 784 - 788
  • [23] Hydrothermal syntheses and crystal structures of bimetallic cluster complexes [{Cd(phen)2}2V4O12]•5H2O and [Ni(phen)3]2[V4O12]•17.5H2O
    Qi, YJ
    Wang, YH
    Li, HM
    Cao, MH
    Hu, CW
    Wang, EB
    Hu, NH
    Jia, HQ
    JOURNAL OF MOLECULAR STRUCTURE, 2003, 650 (1-3) : 123 - 129
  • [24] A Dinuclear Ni(II) Complex [Ni2(Htda)2(H2O)6]•4H2O: Synthesis, Crystal Structure and Properties
    Zhou Xin-Hui
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2010, 26 (05) : 801 - 806
  • [25] Infrared and electronic spectroscopy of p-C6H4Cl2+-Ln clusters with L = Ar, N2, H2O, and p-C6H4Cl2
    Chakraborty, Shamik
    Patzer, Alexander
    Lagutschenkov, Anita
    Langer, Judith
    Dopfer, Otto
    INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 2010, 297 (1-3) : 85 - 95
  • [26] Niobium uptake by {P2W12} polyoxoanion with [NbO(C2O4)2(H2O)2]- as Nb source
    Shmakova, Alexandra A.
    Sukhikh, Taisiya S.
    Volchek, Victoria V.
    Yanshole, Vadim
    Stass, Dmitri, V
    Filatov, Eugeniy Yu
    Glebov, Eugeniy M.
    Abramov, Pavel A.
    Sokolov, Maxim N.
    INORGANICA CHIMICA ACTA, 2020, 502 (502)
  • [27] Synthesis, characterization and structure of (NH4)4[Zn5VIV4VV16O56H2(H2O)4] with a novel V5O14 layer
    Yuan, Youyou
    Wang, Xiaoge
    Chen, Pohua
    Sun, Junliang
    DALTON TRANSACTIONS, 2019, 48 (15) : 4906 - 4911
  • [28] The structure of a new octahedral fluoride complex of niobium (Me4N)2[Nb6F6Br6(H2O)2Cl4]·6H2O
    N. G. Naumov
    S. Cordier
    C. Perrin
    S. B. Artemkina
    Journal of Structural Chemistry, 2008, 49 : 1124 - 1127
  • [29] THE STRUCTURE OF A NEW OCTAHEDRAL FLUORIDE COMPLEX OF NIOBIUM (Me4N)2[Nb6F6Br6(H2O)2Cl4]•6H2O
    Naumov, N. G.
    Cordier, S.
    Perrin, C.
    Artemkina, S. B.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2008, 49 (06) : 1124 - 1127
  • [30] Crystal structure of Cs2[Mo10S10O10(OH)10(H2O)4](C4H2S(PO2H)2)a™21H2O
    Ogienko, D. S.
    Smolentsev, A. I.
    Konchenko, S. N.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2015, 56 (04) : 762 - 764
12345