Introductory lecture: sunlight-driven water splitting and carbon dioxide reduction by heterogeneous semiconductor systems as key processes in artificial photosynthesis

被引:101
作者
Hisatomi, Takashi [1 ,2 ]
Domen, Kazunari [1 ,2 ]
机构
[1] Univ Tokyo, Sch Engn, Dept Chem Syst Engn, Bunkyo Ku, 7-3-1 Hongo, Tokyo 1138656, Japan
[2] Japan Technol Res Assoc Artificial Photosynthet C, Chiyoda Ku, 2-11-9 Iwamotocho, Tokyo 1010032, Japan
基金
日本学术振兴会;
关键词
HYDROGEN EVOLUTION PHOTOCATALYST; VISIBLE-LIGHT IRRADIATION; LAYERED DOUBLE HYDROXIDES; PARTICLE TRANSFER METHOD; REDUCED GRAPHENE OXIDE; Z-SCHEME; ELECTRON MEDIATOR; PEROVSKITE PHOTOVOLTAICS; AQUEOUS SUSPENSIONS; CODOPED SRTIO3;
D O I
10.1039/c6fd00221h
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Both solar water splitting and carbon dioxide reduction using semiconductor systems have been studied as important components of artificial photosynthesis. This paper describes the various photovoltaic-powered electrochemical, photoelectrochemical and photocatalytic processes. An overview of the state-of-the-art is presented along with a summary of recent research approaches. A concept developed by our own research group in which fixed particulate photocatalysts are applied to scalable solar water splitting is discussed. Finally, a description of a possible artificial photosynthesis plant is presented, along with a discussion of the economic aspects of operating such a plant and potential reactor designs.
引用
收藏
页码:11 / 35
页数:25
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