Crystalline 1H-1,2,3-Triazol-5-ylidenes: New Stable Mesoionic Carbenes (MICs)

被引：369

作者：

Guisado-Barrios, Gregorio ^{[1
]}

Bouffard, Jean ^{[1
]}

Donnadieu, Bruno ^{[1
]}

Bertrand, Guy ^{[1
]}

机构：

[1] Univ Calif Riverside, Dept Chem, CNRS, Joint Res Chem Lab,UMI 2957, Riverside, CA 92521 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 28期

基金：

美国国家科学基金会;

关键词：

carbenes; carbene ligands; click chemistry; mesoionic compounds; triazoles; N-HETEROCYCLIC CARBENES; PALLADIUM(II) PYRAZOLIN-4-YLIDENES; COORDINATION CHEMISTRY; LIGAND PROPERTIES; COMPLEXES; NHC; IMIDAZOLIUM; METATHESIS; REMOTE; CURIOSITIES;

D O I：

10.1002/anie.201001864

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Figure Persentation Click makes MICs: A short modular synthesis allows the preparation of novel stable heterocycles that feature a lone pair of electrons on a carbon center. The donor properties of these mesoionic com-pounds are greater than those of classical N-heterocyclic carbenes; they are accessible by deprotonation of the corresponding conjugate acids using comparatively mild bases. © 2010 Wlley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：4759 / 4762

页数：4

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