Precisely Controlling Nanochannels of Graphene Oxide Membranes through Lignin-Based Cation Decoration for Dehydration of Biofuels

被引：38

作者：

Guan, Kecheng ^{[1
]}

Liu, Quan ^{[1
]}

Ji, Yufan ^{[1
]}

Zhang, Mengchen ^{[1
]}

Wu, Yulin ^{[1
]}

Zhao, Jing ^{[1
]}

Liu, Gongping ^{[1
]}

Jin, Wanqin ^{[1
]}

机构：

[1] Nanjing Tech Univ, Coll Chem Engn, Jiangsu Natl Synerget Innovat Ctr Adv Mat, State Key Lab Mat Oriented Chem Engn, 5 Xinmofan Rd, Nanjing 210009, Jiangsu, Peoples R China

来源：

CHEMSUSCHEM | 2018年 / 11卷 / 14期

基金：

中国国家自然科学基金;

关键词：

biofuels; dehydration; graphene; membranes; separations; SELF-ASSEMBLY DRIVEN; SEPARATION PERFORMANCE; WATER; ULTRATHIN; CHANNELS; FILMS;

D O I：

10.1002/cssc.201800479

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Lignin-based cations introduced into graphene oxide (GO) have been found to bring about stabilization of the nanostructure and the active sites and to give rise to various interactions for subsequent modification with polyelectrolyte and nanospacers, with a view to precisely controlling the nanochannels of the GO-based membranes. The resulting membranes exhibited excellent performance in biofuel dehydration with water flux of 4000-6000 gm(-2) h(-1), which exceeds that of the state-of-the-art polymeric and GO-based membranes.

引用

页码：2315 / 2320

页数：6

共 36 条

[1] Graphene oxide membranes on ceramic hollow fibers - Microstructural stability and nanofiltration performance [J].

Aba, Nor Farah Diana ;

Chong, Jeng Yi ;

Wang, Bo ;

Mattevi, Cecilia ;

Li, K. .

JOURNAL OF MEMBRANE SCIENCE, 2015, 484 :87-94

[2]

Abraham J, 2017, NAT NANOTECHNOL, V12, P546, DOI [10.1038/nnano.2017.21, 10.1038/NNANO.2017.21]

[3]

[Anonymous], 2016, Angew. Chem, DOI DOI 10.1002/ANGE.201600438

[4] Ion sieving in graphene oxide membranes via cationic control of interlayer spacing [J].

Chen, Liang ;

Shi, Guosheng ;

Shen, Jie ;

Peng, Bingquan ;

Zhang, Bowu ;

Wang, Yuzhu ;

Bian, Fenggang ;

Wang, Jiajun ;

Li, Deyuan ;

Qian, Zhe ;

Xu, Gang ;

Liu, Gongping ;

Zeng, Jianrong ;

Zhang, Lijuan ;

Yang, Yizhou ;

Zhou, Guoquan ;

Wu, Minghong ;

Jin, Wanqin ;

Li, Jingye ;

Fang, Haiping .

NATURE, 2017, 550 (7676) :415-418

[5] The chemistry of graphene oxide [J].

Dreyer, Daniel R. ;

Park, Sungjin ;

Bielawski, Christopher W. ;

Ruoff, Rodney S. .

CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) :228-240

[6] Functionalization of Graphene: Covalent and Non-Covalent Approaches, Derivatives and Applications [J].

Georgakilas, Vasilios ;

Otyepka, Michal ;

Bourlinos, Athanasios B. ;

Chandra, Vimlesh ;

Kim, Namdong ;

Kemp, K. Christian ;

Hobza, Pavel ;

Zboril, Radek ;

Kim, Kwang S. .

CHEMICAL REVIEWS, 2012, 112 (11) :6156-6214

[7] 3D nanoporous crystals enabled 2D channels in graphene membrane with enhanced water purification performance [J].

Guan, Kecheng ;

Zhao, Di ;

Zhang, Mengchen ;

Shen, Jie ;

Zhou, Guanyu ;

Liu, Gongping ;

Jin, Wanqin .

JOURNAL OF MEMBRANE SCIENCE, 2017, 542 :41-51

[8] Ultrathin Graphene Nanofiltration Membrane for Water Purification [J].

Han, Yi ;

Xu, Zhen ;

Gao, Chao .

ADVANCED FUNCTIONAL MATERIALS, 2013, 23 (29) :3693-3700

[9] Enabling Graphene Oxide Nanosheets as Water Separation Membranes [J].

Hu, Meng ;

Mi, Baoxia .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2013, 47 (08) :3715-3723

[10] Graphene oxide nanosheet: an emerging star material for novel separation membranes [J].

Huang, Hubiao ;

Ying, Yulong ;

Peng, Xinsheng .

JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (34) :13772-13782

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