Solvothermal construction of a coordination polymer around in situ generated pyroglutamic acid:: Preparation, crystal structure, and magnetic behavior of [Mn(C5H6NO3)2]∞

被引:42
作者
Gutschke, SOH [1 ]
Price, DJ [1 ]
Powell, AK [1 ]
Wood, PT [1 ]
机构
[1] Univ E Anglia, Sch Chem Sci, Norwich NR4 7TJ, Norfolk, England
关键词
D O I
10.1021/ic9912427
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Solvothermal Construction of a Coordination Polymer around in Situ Generated Pyroglutamic Acid: Preparation, Crystal Structure, and Magnetic Behavior of [Mn(C5H6NO3)(2)](infinity) In situ solvothermal dehydration of glutamic acid followed by coordination to Mn(II) leads to formation of an infinite chain, the magnetic behavior of which has been measured and modeled. [GRAPHICS]
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页码:3705 / +
页数:4
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