RAFT Synthesis of Sterically Stabilized Methacrylic Nanolatexes and Vesicles by Aqueous Dispersion Polymerization

被引：289
作者：
Li, Yuting [1 ]
Armes, Steven P. [1 ]
机构：
[1] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 24期
基金：
英国工程与自然科学研究理事会;
关键词：
block copolymers; dispersion polymerization; latexes; RAFT; vesicles; TRANSFER RADICAL POLYMERIZATION; WATER-SOLUBLE ALKOXYAMINE; AB-INITIO EMULSION; N-BUTYL ACRYLATE; LOW MOLAR-MASS; MINIEMULSION POLYMERIZATION; TRIBLOCK COPOLYMERS; BLOCK-COPOLYMERS; LATEX-PARTICLES; SURFACTANT-FREE;
D O I：
10.1002/anie.201001461
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) Size control: Sterically stabilized methacrylic nanolatexes are readily prepared by aqueous dispersion polymerization using RAFT reactions (see scheme; CTA = chain transfer agent). Varying the length of the poly(HPMA) chains allows precise size control of the nanolatex particles. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：4042 / 4046
页数：5
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