A new porous Co(ii)-metal-organic framework for high sorption selectivity and affinity to CO2 and efficient catalytic oxidation of benzyl alcohols to benzaldehydes

被引:30
作者
Wu, Yun-Long [1 ,2 ,3 ]
Yang, Rong-Rong [1 ]
Yang, Guo-Ping [2 ,3 ]
Yan, Yang-Tian [1 ]
Su, Xiao-Lei [1 ]
He, Xin-Hai [1 ]
Song, Yan-Yan [1 ]
Ma, Zheng-Sheng [2 ,3 ]
Wang, Yao-Yu [2 ,3 ]
机构
[1] Xian Polytech Univ, Sch Mat Sci & Engn, Xian 710048, Peoples R China
[2] Northwest Univ, Coll Chem & Mat Sci, Shaanxi Key Lab Phys Inorgan Chem, Key Lab Synthet & Nat Funct Mol,Minist Educ, Xian 710127, Peoples R China
[3] Northwest Univ, Sch Chem Engn, Xian 710127, Peoples R China
基金
中国博士后科学基金;
关键词
METAL-ORGANIC FRAMEWORKS; VISIBLE-LIGHT; AEROBIC OXIDATION; CARBONYL-COMPOUNDS; ALDEHYDES; CAPTURE; DEHYDROGENATION; NANOPARTICLES; ADSORPTION; CONVERSION;
D O I
10.1039/d1ce00250c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Herein, we report a new 3D porous Co(ii)-based metal-organic framework catalyst (Me2NH2)(2)[Co-3(L)(2)(H2O)(2)]center dot 2DMF (MOF I), which has been successfully prepared by using Co(ii) ions and rigid V-shaped 3,5-di(2,4-dicarboxylphenyl)pyridine (H4L) via the solvothermal reaction. Structural analysis reveals that I displays a porous structure with the pore size of 16.2 x 7.2 angstrom(2) based on the trinuclear [Co-3(COO)(4)(H2O)(2)N-2] secondary building units (SBUs). Gas sorption experiments on the guest free sample I ' reveals a high capacity and selectivity to CO2 over CH4. And further, the catalytic explorations of the I '-catalyzed system (I ': 3 mol%; proline: 40 mol%; CH3CN: 2 mL) reveal that benzyl alcohols with different structures can be efficiently transformed into benzyl alcohols without by-products under mild conditions.
引用
收藏
页码:3717 / 3723
页数:7
相关论文
共 50 条
[1]  
[Anonymous], 2010, BASIC REACTIONS ORGA
[2]   Coordination polymers, metal-organic frameworks and the need for terminology guidelines [J].
Batten, Stuart R. ;
Champness, Neil R. ;
Chen, Xiao-Ming ;
Garcia-Martinez, Javier ;
Kitagawa, Susumu ;
Ohrstrom, Lars ;
O'Keeffe, Michael ;
Suh, Myunghyun Paik ;
Reedijk, Jan .
CRYSTENGCOMM, 2012, 14 (09) :3001-3004
[3]   Selective Benzyl Alcohol Oxidation over Pd Catalysts [J].
Chan-Thaw, Carine Edith ;
Savara, Aditya ;
Villa, Alberto .
CATALYSTS, 2018, 8 (10)
[4]   Graphene and graphene-like materials in biomass conversion: paving the way to the future [J].
Das, Vijay Kumar ;
Shifrina, Zinaida B. ;
Bronstein, Lyudmila M. .
JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (48) :25131-25143
[5]   Oxidation of benzyl alcohols to aldehydes and ketones under air in water using a polymer supported palladium catalyst [J].
Dell'Anna, Maria Michela ;
Mali, Matilda ;
Mastrorilli, Piero ;
Cotugno, Pietro ;
Monopoli, Antonio .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2014, 386 :114-119
[6]   An excellent dual recycling strategy for the hypervalent iodine/nitroxyl radical mediated selective oxidation of alcohols to aldehydes and ketones [J].
Dohi, Toshifumi ;
Fukushima, Kei-ichiro ;
Kamitanaka, Tohru ;
Morimoto, Koji ;
Takenaga, Naoko ;
Kita, Yasuyuki .
GREEN CHEMISTRY, 2012, 14 (05) :1493-1501
[7]   Zeolite-like metal-organic frameworks (ZMOFs): design, synthesis, and properties [J].
Eddaoudi, Mohamed ;
Sava, Dorina F. ;
Eubank, Jarrod F. ;
Adil, Karim ;
Guillerm, Vincent .
CHEMICAL SOCIETY REVIEWS, 2015, 44 (01) :228-249
[8]   Recent Advances in Cascade Reactions Initiated by Alcohol Oxidation [J].
Faisca Phillips, Ana Maria ;
Pombeiro, Armando J. L. ;
Kopylovich, Maximilian N. .
CHEMCATCHEM, 2017, 9 (02) :217-246
[9]   Neutral ligand TIPA-based two 2D metal-organic frameworks: ultrahigh selectivity of C2H2/CH4 and efficient sensing and sorption of Cr(VI) [J].
Fu, Hong-Ru ;
Zhao, Ying ;
Zhou, Zhan ;
Yang, Xiao-Gang ;
Ma, Lu-Fang .
DALTON TRANSACTIONS, 2018, 47 (11) :3725-3732
[10]   Oxidation of alcohols to carbonyl compounds with CrO3•SiO2 in supercritical carbon dioxide [J].
González-Núñez, ME ;
Mello, R ;
Olmos, A ;
Acerete, R ;
Asensio, G .
JOURNAL OF ORGANIC CHEMISTRY, 2006, 71 (03) :1039-1042