Synthesis, structure, and reactivity of (C5H4SiMe3)2Y{(μ-FC6F4)(μ-Me)B(C6F5)2}:: Tight ion pairing in a cationic lanthanide complex

被引：60

作者：

Song, XJ ^{[1
]}

Thornton-Pett, M ^{[1
]}

Bochmann, M ^{[1
]}

机构：

[1] Univ Leeds, Sch Chem, Leeds LS2 9TH, W Yorkshire, England

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 06期

关键词：

D O I：

10.1021/om971044s

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [Cp'2YMe](2) (Cp' = C5H5, C5H4SiMe3) with B(C6F5)(3) affords the complexes Cp'Y-2{MeB(C6F5)(3)}. The anion is coordinated in a chelating fashion via one ortho-fluorine atom and agostic interactions to two of the methyl hydrogens; the complexes are highly fluxional in solution. They act as initiators for the carbocationic polymerization of isobutene.

引用

页码：1004 / 1006

页数：3

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