Complementarity of small-angle neutron and X-ray scattering methods for the quantitative structural and dynamical specification of dendritic macromolecules

被引：30
作者：
Kuklin, AI
Ozerin, AN
Islamov, AK
Muzafarov, AM
Gordeliy, VI
Rebrov, EA
Ignat'eva, GM
Tatarinova, EA
Mukhamedzyanov, RI
Ozerina, LA
Sharipov, EY
机构：
[1] Enikolopov Inst Synthet Polymer Mat, Moscow 117393, Russia
[2] Joint Inst Nucl Res, Frank Lab Neutron Phys, Dubna 141980, Russia
来源：
JOURNAL OF APPLIED CRYSTALLOGRAPHY | 2003年 / 36卷 / 01期
关键词：
small-angle neutron scattering; small-angle X-ray scattering; dendrimer; structure; solution;
D O I：
10.1107/S0021889803006186
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The structural characteristics of polycarbosilane dendrimers with different molecular architecture were determined in solutions by small angle neutron and X-ray scattering. The same linear dimensions were sized up for the dendrimers both in benzene and chloroform. A solvent molecules penetration inside dendrimer structure in amount up to 30 vol.-% was found from the comparison of the partial and effective scattering volume for the dendrimers in solution.
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页码：679 / 683
页数：5
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