Synthesis of Hexa-peri-hexobenzocoronenes Carrying Linear or Branched Perfluoroalkylated Side Chains

被引：3

作者：

Aebischer, Olivier F. ^{[1
]}

Munoz, David T. ^{[1
]}

Tondo, Patrick ^{[1
]}

Debieux, Jean-Luc ^{[1
]}

Jenny, Titus A. ^{[1
]}

机构：

[1] Univ Fribourg, Dept Chem, CH-1700 Fribourg, Switzerland

来源：

SYNTHESIS-STUTTGART | 2010年 / 07期

关键词：

HBC; perfluoroalkylated substitutions; cross-coupling; cyclodehydrogenation; tandem Sonogashira; HYDROGEN-ATOM TRANSFER; GRIGNARD-REAGENTS; HEXABENZOCORONENES; REACTIVITY; SYSTEMS; HYDROCARBONS; SEGREGATION; COMPLEXES; POLYMERS; STRATEGY;

D O I：

10.1055/s-0029-1218667

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Substituted disc-shaped perfluoroalkylated hexa-peri-hexabenzocoronenes (HBC), known to self-assemble into conducting ordered architectures, were synthesized and characterized. A systematic variation of the linear or branched perfluoroalkylated side chains was performed in order to screen the influence of the lateral chain on their one-dimensional self-aggregation.

引用

页码：1123 / 1140

页数：18