Synthesis of Hexa-peri-hexobenzocoronenes Carrying Linear or Branched Perfluoroalkylated Side Chains

被引:3
|
作者
Aebischer, Olivier F. [1 ]
Munoz, David T. [1 ]
Tondo, Patrick [1 ]
Debieux, Jean-Luc [1 ]
Jenny, Titus A. [1 ]
机构
[1] Univ Fribourg, Dept Chem, CH-1700 Fribourg, Switzerland
来源
SYNTHESIS-STUTTGART | 2010年 / 07期
关键词
HBC; perfluoroalkylated substitutions; cross-coupling; cyclodehydrogenation; tandem Sonogashira; HYDROGEN-ATOM TRANSFER; GRIGNARD-REAGENTS; HEXABENZOCORONENES; REACTIVITY; SYSTEMS; HYDROCARBONS; SEGREGATION; COMPLEXES; POLYMERS; STRATEGY;
D O I
10.1055/s-0029-1218667
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Substituted disc-shaped perfluoroalkylated hexa-peri-hexabenzocoronenes (HBC), known to self-assemble into conducting ordered architectures, were synthesized and characterized. A systematic variation of the linear or branched perfluoroalkylated side chains was performed in order to screen the influence of the lateral chain on their one-dimensional self-aggregation.
引用
收藏
页码:1123 / 1140
页数:18
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