Olefin metathesis is among the most powerful tools for the formation of regio- and steroselective carbon-carbon double bonds. Applying the principles of Green Chemistry to the syntheses of polymers by developing useful strategies to facilitate catalyst and polymer product separation after a polymerization is vital. In the present study, a phase selectively soluble polymer bound second generation Grubbs catalyst was successfully used to carry out ring-opening metathesis polymerization (ROMP) on norbornene and a variety of different exo-norbornene derivatives. Polymers with low ruthenium contamination levels were achieved in comparison to the non-supported Grubbs catalyst which required multiple precipitations. Furthermore, the bound catalyst exhibits similar catalytic activity to its homogenous counterpart.
机构:
CALTECH, Arnold & Mabel Beckman Labs Chem Synth, Div Chem & Chem Engn, Pasadena, CA 91125 USACALTECH, Arnold & Mabel Beckman Labs Chem Synth, Div Chem & Chem Engn, Pasadena, CA 91125 USA
Bielawski, CW
;
Benitez, D
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CALTECH, Arnold & Mabel Beckman Labs Chem Synth, Div Chem & Chem Engn, Pasadena, CA 91125 USACALTECH, Arnold & Mabel Beckman Labs Chem Synth, Div Chem & Chem Engn, Pasadena, CA 91125 USA
Benitez, D
;
Morita, T
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机构:
CALTECH, Arnold & Mabel Beckman Labs Chem Synth, Div Chem & Chem Engn, Pasadena, CA 91125 USACALTECH, Arnold & Mabel Beckman Labs Chem Synth, Div Chem & Chem Engn, Pasadena, CA 91125 USA
Morita, T
;
Grubbs, RH
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CALTECH, Arnold & Mabel Beckman Labs Chem Synth, Div Chem & Chem Engn, Pasadena, CA 91125 USACALTECH, Arnold & Mabel Beckman Labs Chem Synth, Div Chem & Chem Engn, Pasadena, CA 91125 USA
机构:
CALTECH, Arnold & Mabel Beckman Labs Chem Synth, Div Chem & Chem Engn, Pasadena, CA 91125 USACALTECH, Arnold & Mabel Beckman Labs Chem Synth, Div Chem & Chem Engn, Pasadena, CA 91125 USA
Bielawski, CW
;
Benitez, D
论文数: 0引用数: 0
h-index: 0
机构:
CALTECH, Arnold & Mabel Beckman Labs Chem Synth, Div Chem & Chem Engn, Pasadena, CA 91125 USACALTECH, Arnold & Mabel Beckman Labs Chem Synth, Div Chem & Chem Engn, Pasadena, CA 91125 USA
Benitez, D
;
Morita, T
论文数: 0引用数: 0
h-index: 0
机构:
CALTECH, Arnold & Mabel Beckman Labs Chem Synth, Div Chem & Chem Engn, Pasadena, CA 91125 USACALTECH, Arnold & Mabel Beckman Labs Chem Synth, Div Chem & Chem Engn, Pasadena, CA 91125 USA
Morita, T
;
Grubbs, RH
论文数: 0引用数: 0
h-index: 0
机构:
CALTECH, Arnold & Mabel Beckman Labs Chem Synth, Div Chem & Chem Engn, Pasadena, CA 91125 USACALTECH, Arnold & Mabel Beckman Labs Chem Synth, Div Chem & Chem Engn, Pasadena, CA 91125 USA