A Critical Appraisal of RAFT-Mediated Polymerization-Induced Self Assembly

被引:778
|
作者
Canning, Sarah L. [1 ]
Smith, Gregory N. [1 ]
Armes, Steven P. [1 ]
机构
[1] Univ Sheffield, Dept Chem, Dainton Bldg,Brook Hill, Sheffield S3 7HF, S Yorkshire, England
基金
英国工程与自然科学研究理事会;
关键词
AQUEOUS DISPERSION POLYMERIZATION; LIVING RADICAL POLYMERIZATION; COPOLYMER NANO-OBJECTS; ONE-POT SYNTHESIS; FRAGMENTATION-CHAIN TRANSFER; AMPHIPHILIC BLOCK-COPOLYMERS; HYDROPHILIC GRAFT COPOLYMER; POLYELECTROLYTE-STABILIZED NANOPARTICLES; INITIO EMULSION POLYMERIZATION; CROSS-LINKED MICELLES;
D O I
10.1021/acs.macromol.5b02602
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Recently, polymerization-induced self-assembly (PISA) has become widely recognized as a robust and efficient route to produce block copolymer nanoparticles of controlled size, morphology, and surface chemistry. Several reviews of this field have been published since 2012, but a substantial number of new papers have been published in the last three years. In this Perspective, we provide a critical appraisal of the various advantages offered by this approach, while also pointing out some of its current drawbacks: Promising future research directions as well as remaining technical challenges and unresolved problems are briefly highlighted.
引用
收藏
页码:1985 / 2001
页数:17
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