Thermolysis of lanthanide dithiocarbamate complexes

被引：24

作者：

Boncher, William L. ^{[1
]}

Regulacio, Michelle D. ^{[1
]}

Stoll, Sarah L. ^{[1
]}

机构：

[1] Georgetown Univ, Dept Chem, Washington, DC 20057 USA

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2010年 / 183卷 / 01期

基金：

美国国家科学基金会;

关键词：

Lanthanide dithiocarbamate; Lanthanide sulfide; Lanthanide oxysulfide; Lanthanide oxide; SULFIDES; LA; SESQUISULFIDES; NANOPARTICLES; MAGNETISM; METAL; E=S; PR; SE; SM;

D O I：

10.1016/j.jssc.2009.10.003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Polycrystalline lanthanide sulfide materials were formed at low temperatures using a single-source precursor based on the lanthanide dithiocarbamate complex. The synthesis temperatures aye generally lower than standard solid state preparations, avoid toxic sulfurizing gases and provide a convenient route to prepare lanthanide chalcogenide nanoparticles. Depending on the reaction conditions and oxophilicity of the lanthanide, the Sulfide material was formed with oxidized products including oxysulfides, oxysulfates and the oxide. (C) 2009 Elsevier Inc. All rights reserved.

引用

页码：52 / 56

页数：5

共 28 条

[1] THE RELATIVE AFFINITIES OF LIGAND ATOMS FOR ACCEPTOR MOLECULES AND IONS [J].

AHRLAND, S ;

CHATT, J ;

DAVIES, NR .

QUARTERLY REVIEWS, 1958, 12 (03) :265-276

[2] HETEROMETALLIC EU/M(II) BENZENETHIOLATES (M=ZN,CD,HG) - SYNTHESIS, STRUCTURE, AND THERMOLYSIS CHEMISTRY [J].

BREWER, M ;

LEE, J ;

BRENNAN, JG .

INORGANIC CHEMISTRY, 1995, 34 (23) :5919-5924

[3] PYRIDINE COORDINATION-COMPLEXES OF THE DIVALENT YTTERBIUM CHALCOGENOLATES YB(EPH)2 (E=S, SE, TE) [J].

BREWER, M ;

KHASNIS, D ;

BURETEA, M ;

BERARDINI, M ;

EMGE, TJ ;

BRENNAN, JG .

INORGANIC CHEMISTRY, 1994, 33 (13) :2743-2747

[4]

Danielson L., 1984, P 19 INT EN CONV ENG, V4, P2256

[5] HIGH-PRESSURE TH3P4-TYPE POLYMORPHS OF RARE EARTH SESQUICHALCOGENIDES [J].

EATOUGH, NL ;

WEBB, AW ;

HALL, HT .

INORGANIC CHEMISTRY, 1969, 8 (10) :2069-&

[6]

FLAHAUT J, 1979, SELENIDES TELLURIDES, P4

[7] Kinetics of thermal synthesis of cerium sulfides [J].

Gibbard, Kevin B. ;

Allahar, Kerry N. ;

Kolman, David ;

Butt, Darryl P. .

JOURNAL OF NUCLEAR MATERIALS, 2008, 378 (03) :291-298

[8]

Golubkov A. V., 1973, PHYS PROPERTIES CHAL

[9]

GUITTARD M, 1991, PREPARATION RARE EAR, V2, P321

[10] Syntheses, structure, magnetism, and optical properties of the ordered mixed-lanthanide sulfides γ-LnLn′S3 (Ln = La, Ce;: Ln′ = Er, Tm, Yb) [J].

Jin, Geng Bang ;

Choi, Eun Sang ;

Guertin, Robert P. ;

Brooks, James S. ;

Bray, Travis H. ;

Booth, Corwin H. ;

Albrecht-Schmitt, Thomas E. .

CHEMISTRY OF MATERIALS, 2007, 19 (03) :567-574

← 1 2 3 →