Studies on the interaction of photosensitizers and glucose oxidase using capillary electrophoresis

被引:0
|
作者
Hu, P [1 ]
Luo, GA [1 ]
Wang, RJ [1 ]
Dong, RA [1 ]
Song, XQ [1 ]
机构
[1] TSING HUA UNIV,DEPT CHEM,BEIJING 100084,PEOPLES R CHINA
来源
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 1997年 / 18卷 / 09期
关键词
capillary electrophoresis; glucose oxidase; photosensitized oxidation;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The interaction of glucose oxidase (GOD) and four photosensitizers, ZnPcS4, ZnPc(NHCH2COOH)(4), ClAlPcS, and porphyrine-like, were monitored by capillary electrophoresis. GOD, its degenerated products and photosensitizers were simultaneously separated in a buffer of 300 mmol/L berate at pH 8.5 on a commercial CE instrument. By comparison of the electropherograms of GOD as well as the mixture of GOD and photosensitizers without/with irradiation of different time, it was found that photosensitized oxidations between GOD and different photosensitizers have different reaction mechanisms and kinetics.
引用
收藏
页码:1459 / 1461
页数:3
相关论文
共 5 条