A novel colorimetric and fluorescent probe for simultaneous detection of SO32-/HSO3- and HSO4- by different emission channels and its bioimaging in living cells

被引：57

作者：

Yu, Ting ^{[1
]}

Yin, Guoxing ^{[1
]}

Niu, Tingting ^{[2
]}

Yin, Peng ^{[1
]}

Li, Haitao ^{[1
]}

Zhang, Youyu ^{[1
]}

Chen, Haimin ^{[2
]}

Zeng, Ying ^{[1
]}

Yao, Shouzhuo ^{[1
]}

机构：

[1] Hunan Normal Univ, Coll Chem & Chem Engn, Minist Educ, Key Lab Chem Biol & Tradit Chinese Med Res, Changsha 410081, Hunan, Peoples R China

[2] Ningbo Univ, Key Lab Marine Biotechnol Zhejiang Prov, Ningbo 315211, Zhejiang, Peoples R China

来源：

TALANTA | 2018年 / 176卷

基金：

中国国家自然科学基金;

关键词：

Fluorescent probe; Simultaneous detection; SO2; Sodium hydrosulfate; TURN-ON PROBE; SULFUR-DIOXIDE DERIVATIVES; SO2; DERIVATIVES; RATIOMETRIC DETECTION; SELECTIVE DETECTION; RAPID DETECTION; SCHIFF-BASE; SULFITE; BISULFITE; SENSOR;

D O I：

10.1016/j.talanta.2017.08.001

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

novel fluorescent probe (E)-3-ethyl-2-(4-hydroxystyry1)-1,1-di-methyl-1H-benzo-[e]indolium iodide (probe EDB) based on benzo[e]indolium was synthesized, which provided the simultaneous detection of SO32-/HSO3 and HSO4- ion with different emission channels. Based on the principle of ion-induced rotation-displaced H aggregates, when treated with NaHSO4, a fluorescence enhancement at 580 nm was observed with the excitation wavelength at 420 nm. While, in the advantage of the nucleophilic addition of SO32- to the vinyl group, strong fluorescence was obtained at 455 nm when treated with Na2SO3 with the excitation wavelength at 320 nm, along with obvious color change by naked eyes. So the probe could be applied to sense SO32-/HSO3- and HSO4- ion via different excited and emission channels simultaneously. The probe was also applicable for fluorescence imagings of bisulfite and hydrosulfate in HeLa cells.

引用

页码：1 / 7

页数：7

共 57 条

[1]

Ajayaghosh A, 2002, ANGEW CHEM INT EDIT, V41, P1766, DOI 10.1002/1521-3773(20020517)41:10<1766::AID-ANIE1766>3.0.CO

[2]

2-4

[3] A controlled supramolecular approach toward cation-specific chemosensors: Alkaline earth metal ion-driven exciton signaling in squaraine tethered podands [J].

Arunkumar, E ;

Chithra, P ;

Ajayaghosh, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (21) :6590-6598

[4] MECHANISMS OF RESISTANCE TO SULFUR-DIOXIDE IN CUCURBITACEAE [J].

BRESSAN, RA ;

WILSON, LG ;

FILNER, P .

PLANT PHYSIOLOGY, 1978, 61 (05) :761-767

[5]

Chan J, 2012, NAT CHEM, V4, P973, DOI [10.1038/NCHEM.1500, 10.1038/nchem.1500]

[6] Efficient fluorescent chemosensors for HSO4- based on a strategy of anion-induced rotation-displaced H-aggregates [J].

Chang, Jiajia ;

Lu, Yan ;

He, Song ;

Liu, Chang ;

Zhao, Liancheng ;

Zeng, Xianshun .

CHEMICAL COMMUNICATIONS, 2013, 49 (56) :6259-6261

[7] A highly sulfite-selective ratiometric fluorescent probe based on ESIPT [J].

Chen, Song ;

Hou, Peng ;

Wang, Jianxiu ;

Song, Xiangzhi .

RSC ADVANCES, 2012, 2 (29) :10869-10873

[8] Selective, Highly Sensitive Fluorescent Probe for the Detection of Sulfur Dioxide Derivatives in Aqueous and Biological Environments [J].

Chen, Wenqiang ;

Fang, Qian ;

Yang, Dalei ;

Zhang, Hongyan ;

Song, Xiangzhi ;

Foley, James .

ANALYTICAL CHEMISTRY, 2015, 87 (01) :609-616

[9] Chromogenic and Fluorogenic Signaling of Sulfite by Selective Deprotection of Resorufin Levulinate [J].

Choi, Myung Gil ;

Hwang, Jiyoung ;

Eor, Suyoung ;

Chang, Suk-Kyu .

ORGANIC LETTERS, 2010, 12 (24) :5624-5627

[10] Ion sensing coupled to resonance energy transfer: A highly selective and sensitive ratiometric fluorescent chemosensor for Ag(I) by a modular approach [J].

Coskun, A ;

Akkaya, EU .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (30) :10464-10465

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