Kinetics and mechanism of electron-transfer reactions : Oxidation of dimethyl sulfoxide by iodine monochloride in acid aqueous medium

被引：0

作者：

Sharma, Seema ^{[1
]}

Khandelwal, C. L. ^{[1
]}

Sharma, P. D. ^{[1
]}

机构：

[1] Univ Rajasthan, Dept Chem, Jaipur 302004, Rajasthan, India

来源：

JOURNAL OF THE INDIAN CHEMICAL SOCIETY | 2010年 / 87卷 / 05期

关键词：

Iodine monochloride; kinetics; electron transfer reaction; oxidation; dimethyl sulfoxide; mechanism; OSMIUM(VIII) CATALYZED OXIDATION; ALKALINE-MEDIUM; DIPHENYL SULFOXIDES; ACETIC-ACID; BENZENESULFONAMIDES; DIMETHYLSULFOXIDE;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The kinetics of oxidation of dimethyl sulfoxide by iodine monochloride has been studied in acid aqueous medium. The reaction stoichiometry is represented by [GRAPHICS] The reaction exhibits first order kinetics with respect to the oxidant but a complex order with the substrate. The rate law is given by - d[ICl]/dt = kKKh[ICl][DMSO]/K-h + [H+] + KKh[DMSO] Thermodynamic parameters have also been evaluated.

引用

页码：579 / 582

页数：4