Properties and Catalytic Activities of New Easily-Made Amphiphilic Phosphanes for Aqueous Organometallic Catalysis

被引：21

作者：

Ferreira, Michel ^{[1
,2
,6
]}

Bricout, Herve ^{[1
,2
,6
]}

Azaroual, Nathalie ^{[1
,3
,7
]}

Gaillard, Cedric ^{[5
]}

Landy, David ^{[1
,4
]}

Tilloy, Sebastien ^{[1
,2
,6
]}

Monflier, Eric ^{[1
,2
,6
]}

机构：

[1] Univ Lille Nord France, F-59000 Lille, France

[2] UCCS, UArtois, F-62300 Lens, France

[3] UDSL, Fac Pharm, F-59006 Lille, France

[4] ULCO, LSOE, F-59140 Dunkerque, France

[5] INRA, UR Biopolymeres Interact Assemblages 1268, F-44316 Nantes 3, France

[6] CNRS, UMR 8181, F-75700 Paris, France

[7] CNRS, UMR 8009, F-75700 Paris, France

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2010年 / 352卷 / 07期

关键词：

amphiphiles; aqueous-phase catalysis; phosphane ligands; Tsuji-Trost reaction; water; PHASE-TRANSFER LIGANDS; M-TPPTC LIGAND; BIPHASIC HYDROFORMYLATION; 2-PHASE HYDROFORMYLATION; DEPROTECTIVE METHOD; RHODIUM COMPLEXES; PHOSPHINE-LIGANDS; SELECTIVITY; CHAIN; HYDROGENATION;

D O I：

10.1002/adsc.201000014

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Mono- and disulfonated amphiphilic versions of triphenylphosphane (PPh3) and cyclohexyl-(phenyl)phosphane were easily synthesized from commercial reagents and sulfuric acid. The behaviour of these phosphanes in solution was investigated by surface tension, isothermal titration calorimetry, nuclear magnetic resonance and cryo-transmission electron microscopy. Two different supramolecular assemblies were evidenced according to the degree of sulfonation. The monosulfonated phosphanes formed well organized micelle-like aggregates while the disulfonated phosphanes formed heterogeneous and disorganized vesicle-like assemblies. The efficiency of these amphiphilic phosphanes was evaluated in the aqueous biphasic, palladium-catalyzed cleavage of allyl alkyl carbonates.

引用

页码：1193 / 1203

页数：11

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