Boration of an α,β-enone using a diboron promoted by a copper(I)-phosphine mixture catalyst

被引：316
作者：
Ito, H
Yamanaka, H
Tateiwa, J
Hosomi, A [1 ]
机构：
[1] Univ Tsukuba, Grad Sch Pure & Appl Sci, Dept Chem, Tsukuba, Ibaraki 3058571, Japan
[2] Inst Mol Sci, Res Ctr Mol Mat, Okazaki, Aichi 4448585, Japan
来源：
TETRAHEDRON LETTERS | 2000年 / 41卷 / 35期
关键词：
copper and compounds; boron and compounds; enones; catalysts;
D O I：
10.1016/S0040-4039(00)01161-8
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The Cu(I)-catalyzed boration of an alpha,beta-enone using a diboron is described. Combination of a Cu(I) salt and tributylphosphine is an effective catalyst system, though the individual use of Cu(I) and tributylphosphine is not active for the reaction. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：6821 / 6825
页数：5
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