Synthesis and crystal structure of 3-benzoyl-7,7-dimethyl-4-phenyl-2-phenylamino-4,6,7,8-tetrahydro-chromen-5-one

被引：0

作者：

Li Ming ^{[1
]}

Sun En-Tao ^{[1
]}

Wen Li-Rong ^{[1
]}

Wang Shu-Wen ^{[1
]}

机构：

[1] Ocean Univ Sci & Technol, Coll Chem & Mol Engn, Qingdao 266042, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2007年 / 26卷 / 04期

关键词：

tetrahydrochromene; thioamides; MCRs; crystal structure;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound (C30H27NO3) was synthesized via a one-pot procedure starting fr om beta-benzoylthioacetanilide, benzaldehyde and 5,5-dimethyl-1,3-cyclohexanedione, and its structure was determined by single-crystal X-ray diffraction analysis. The crystal belongs to triclinic system, space group Pl, with a = 6.325(2), b = 11.243(3), c = 17.553(4) angstrom, a = 87.306(4), beta = 80.822(4), gamma = 77.798(4)degrees, V = 1204.2(5) angstrom(3), Z = 2, M-r = 449.53, D-c = 1.240 g/cm(3), mu = 0.080 mm(-1) F(000) = 476, the final R = 0.0459 and wR = 0.0970 for 2301 observed reflections with I > 2 sigma(I).

引用

页码：385 / 388

页数：4

共 19 条

[1] Stereoselective synthesis of bridged azepine derivatives via polyfunctionalized spiroannulated thiophene. Novel rearrangement of oxime esters [J].

Bogdanowicz-Szwed, K ;

Grochowski, J ;

Obara, A ;

Rys, B ;

Serda, P .

JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (21) :7205-7208

[2]

BOGDANOWICZSZWED K, 1990, LIEBIGS ANN CHEM, P1147

[3]

BRITSUN VN, 2005, CHEM HETEROCYCL COMP, V41, P105

[4]

Gao Y, 2001, CHIN J STRUCT CHEM, V20, P505

[5] KETENDERIVATE .12. BEITRAGE ZUR CHEMIE DER DITHIOCARBONSAUREESTER UND KETENMERCAPTALE [J].

GOMPPER, R ;

SCHAEFER, H .

CHEMISCHE BERICHTE-RECUEIL, 1967, 100 (02) :591-&

[6] Synthesis and biological activity of a novel series of nonsteroidal, peripherally selective androgen receptor antagonists derived from 1,2-dihydropyridino[5,6-g]quinolines [J].

Hamann, LG ;

Higuchi, RI ;

Zhi, L ;

Edwards, JP ;

Wang, XN ;

Marschke, KB ;

Kong, JW ;

Farmer, LJ ;

Jones, TK .

JOURNAL OF MEDICINAL CHEMISTRY, 1998, 41 (04) :623-639

[7]

Hassanien AA, 1999, J INDIAN CHEM SOC, V76, P350

[8]

HATOKEYAMA S, 1998, J CHEM SOC CHEM COMM, P1022

[9] A novel three-component synthesis of triazinothiazolones [J].

Holla, BS ;

Malini, KV ;

Sarojini, BK ;

Poojary, B .

SYNTHETIC COMMUNICATIONS, 2005, 35 (03) :333-340

[10] Reactions of β-keto thioamides with α,β-unsaturated aldehydes.: Synthesis of 6-hydroxypiperidine-2-thiones and 6H-thiopyrans [J].

Jagodzinski, TS ;

Sosnicki, JG ;

Wesolowska, A .

TETRAHEDRON, 2003, 59 (23) :4183-4192

← 1 2 →